Palladium-Catalyzed Direct and Regioselective C-H Bond Functionalization/Oxidative Acetoxylation of Indoles

被引:83
|
作者
Choy, Pui Ying
Lau, Chak Po
Kwong, Fuk Yee [1 ]
机构
[1] Hong Kong Polytech Univ, State Key Lab Chirosci, Kowloon, Hong Kong, Peoples R China
来源
JOURNAL OF ORGANIC CHEMISTRY | 2011年 / 76卷 / 01期
关键词
CROSS-COUPLING REACTIONS; DERIVATIVES; REACTIVITY; CHEMISTRY; ARYLATION; LIGANDS;
D O I
10.1021/jo101584k
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
The first general examples of palladium-catalyzed direct and selective oxidative C3-acetoxylation of indoles are presented. The mild reaction conditions (70 degrees C and with weak base, KOAc) in this indole C-H-acetoxylation are notable.
引用
收藏
页码:80 / 84
页数:5
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