The Synthesis of Chiral Periodic Organosilica Materials with Ultrasmall Mesopores

被引：18

作者：

Wu, Xiaowei ^{[1
]}

Blackburn, Thomas ^{[1
]}

Webb, Jonathan D. ^{[1
]}

Garcia-Bennett, Alfonso E. ^{[2
]}

Crudden, Cathleen M. ^{[1
]}

机构：

[1] Queens Univ, Dept Chem, Kingston, ON K7L 3N6, Canada

[2] Uppsala Univ, Dept Engn Sci, Angstrom Lab, S-75121 Uppsala, Sweden

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2011年 / 50卷 / 35期

基金：

加拿大创新基金会; 瑞典研究理事会; 加拿大自然科学与工程研究理事会;

关键词：

chirality; helical structures; microporous materials; organosilica; silicon; MESOSTRUCTURED SILICA; NITROGEN ADSORPTION; ORGANIC GROUPS; BINOL; NANOFIBERS; ROUTE;

D O I：

10.1002/anie.201101909

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Helical organosilica materials were synthesized for the first time using a novel binaphthyl-based chiral co-monomer in less than 1 hour. The incorporation of a chiral co-monomer in the wall was shown to influence the curvature of the helical materials. As the amount of the chiral co-monomer was increased, the degree of curvature increased, illustrating the importance of this monomer to the overall morphology. © 2011 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：8095 / 8099

页数：5

共 50 条

[31] Synthesis of a spirobifluorene-bridged allylsilane precursor for periodic mesoporous organosilica
Tanaka, Natsuko
Mizoshita, Norihiro
Maegawa, Yoshifumi
Tani, Takao
Inagaki, Shinji
Jorapur, Yogesh R.
Shimada, Toyoshi
CHEMICAL COMMUNICATIONS, 2011, 47 (17) : 5025 - 5027
[32] Periodic Mesoporous Organosilica Nanorice
Mohanty, Paritosh
Landskron, Kai
NANOSCALE RESEARCH LETTERS, 2009, 4 (02): : 169 - 172
[33] Homogenization of Periodic Structured Materials With Chiral Properties
Ouchetto, Ouail
El Majd, Badr Abou
Ouchetto, Hassania
Essakhi, Brahim
Zouhdi, Said
IEEE TRANSACTIONS ON ANTENNAS AND PROPAGATION, 2016, 64 (05) : 1751 - 1758
[34] Grafting of poly(N-isopropylacrylamide) brushes on the surface of cylindrical mesopores of periodic mesoporous organosilica via atom transfer radical polymerization
Manchanda, Amanpreet
Kruk, Michal
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2015, 250
[35] Mesoporous silica and organosilica materials - Review of their synthesis and organic functionalization
Asefa, Tewodros
Tao, Zhimin
CANADIAN JOURNAL OF CHEMISTRY, 2012, 90 (12) : 1015 - 1031
[36] Periodic Mesoporous Organosilica (PMO) Materials with Uniform Spherical Core-Shell Structure
Haffer, Stefanie
Tiemann, Michael
Froeba, Michael
CHEMISTRY-A EUROPEAN JOURNAL, 2010, 16 (34) : 10447 - 10452
[37] Influence of Synthesis Conditions on Properties of Ethane-Bridged Periodic Mesoporous Organosilica Materials as Revealed by Spin-Probe EPR
Lin, Feng
Mertens, Myrjam
Cool, Pegie
Van Doorslaer, Sabine
JOURNAL OF PHYSICAL CHEMISTRY C, 2013, 117 (44): : 22723 - 22731
[38] Hybrid Inclusion Materials Based on Chiral Nematic Mesoporous Organosilica with Incorporated Cyclodextrin Receptors
Szymkowiak, Joanna K.
CHEMISTRY-A EUROPEAN JOURNAL, 2025, 31 (11)
[39] Simple Systematic Synthesis of Periodic Mesoporous Organosilica Nanoparticles with Adjustable Aspect Ratios
Mohanty, Paritosh
Landskron, Kai
NANOSCALE RESEARCH LETTERS, 2009, 4 (12): : 1524 - 1529
[40] Periodic mesoporous organosilica for chromatographic stationary phases: From synthesis strategies to applications
Liu, Bei
Li, Hui
Quan, Kaijun
Chen, Jia
Qiu, Hongdeng
TRAC-TRENDS IN ANALYTICAL CHEMISTRY, 2023, 158

← 1 2 3 4 5 →