The Synthesis of Chiral Periodic Organosilica Materials with Ultrasmall Mesopores

被引:18
|
作者
Wu, Xiaowei [1 ]
Blackburn, Thomas [1 ]
Webb, Jonathan D. [1 ]
Garcia-Bennett, Alfonso E. [2 ]
Crudden, Cathleen M. [1 ]
机构
[1] Queens Univ, Dept Chem, Kingston, ON K7L 3N6, Canada
[2] Uppsala Univ, Dept Engn Sci, Angstrom Lab, S-75121 Uppsala, Sweden
基金
加拿大创新基金会; 瑞典研究理事会; 加拿大自然科学与工程研究理事会;
关键词
chirality; helical structures; microporous materials; organosilica; silicon; MESOSTRUCTURED SILICA; NITROGEN ADSORPTION; ORGANIC GROUPS; BINOL; NANOFIBERS; ROUTE;
D O I
10.1002/anie.201101909
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Helical organosilica materials were synthesized for the first time using a novel binaphthyl-based chiral co-monomer in less than 1 hour. The incorporation of a chiral co-monomer in the wall was shown to influence the curvature of the helical materials. As the amount of the chiral co-monomer was increased, the degree of curvature increased, illustrating the importance of this monomer to the overall morphology. © 2011 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码:8095 / 8099
页数:5
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