Periodic mesoporous organosilica for chromatographic stationary phases: From synthesis strategies to applications

被引：10
|
作者：
Liu, Bei [1 ,2 ]
Li, Hui [1 ]
Quan, Kaijun [1 ]
Chen, Jia [1 ,2 ]
Qiu, Hongdeng [1 ,2 ]
机构：
[1] Chinese Acad Sci, Lanzhou Inst Chem Phys, CAS Key Lab Chem Northwestern Plant Resources, Key Lab Nat Med Gansu Prov, Lanzhou 730000, Peoples R China
[2] Univ Chinese Acad Sci, Beijing 100049, Peoples R China
来源：
TRAC-TRENDS IN ANALYTICAL CHEMISTRY | 2023年 / 158卷
基金：
中国国家自然科学基金;
关键词：
Periodic mesoporous organosilicas; Stationary phases; HPLC; Monolithic column; Bridged silsesquioxanes; PERFORMANCE LIQUID-CHROMATOGRAPHY; SILICA MICROSPHERES; SPHERES; SEPARATION; PARTICLE; NANOPARTICLES; MORPHOLOGY; MONOLITH; UNIFORM; PACKING;
D O I：
10.1016/j.trac.2022.116895
中图分类号：
O65 [分析化学];
学科分类号：
070302 ; 081704 ;
摘要：
Periodic mesoporous organosilica (PMO) materials with organic functionalities in mesoporous frame-works have received a lot of attention in multiple fields. This particular review focuses on the improvement of chromatographic separation benefitting from the superiority of PMO stationary phases, including packed columns and monolithic columns. To understand the correlation between PMO chro-matographic stationary phase compositions and chromatographic performance, we summarize the functional bridges, synthesis methods, and modification methods. The research directions for further development of a more highly efficient PMO chromatographic column are outlooked.(c) 2022 Elsevier B.V. All rights reserved.
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页数：13
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