1,1-diethyl-1-germa-2,3,4,5-tetra-tert-butyl-2,3,4,5-tetraphospholane (C2H5)2Ge(tBuP)4, molecular and crystal structure

被引：0

作者：

Binder, H ^{[1
]}

Schuster, B ^{[1
]}

Schwarz, W ^{[1
]}

Klinkhammer, KW ^{[1
]}

机构：

[1] Univ Stuttgart, Inst Anorgan Chem, D-70569 Stuttgart, Germany

来源：

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 1999年 / 625卷 / 05期

关键词：

1-germa-2,3,4,5-tetraphospholane; NMR data; crystal structure;

D O I：

10.1002/(SICI)1521-3749(199905)625:5<699::AID-ZAAC699>3.3.CO;2-H

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction of the diphosphide K-2[(tBuP)(4)] THF (1) with the germanium(IV) compound (C2H5)(2)GeCl2 leads via a [4 + 1]-cyclo-condensation reaction to 1,1-diethyl-1-germa-2,3,4,5-tetra-tert-butyl-2,3,4,5-tetraphospholane (C2H5)(2)Ge(tBuP)(4) (2) with the 5-membered GeP4 ring system. 2 could be characterized P-31 NMR spectroscopically, mass spectrometrically and by a single crystal structure analysis.

引用

页码：699 / 701

页数：3

共 50 条

[41] CONTRIBUTION ON THE STRUCTURAL CHEMISTRY OF PHOSPHORUS-CONTAINING CHAINS AND RINGS .14. THE MOLECULAR AND CRYSTAL-STRUCTURE OF 1,2,4,5-TETRA-TERT-BUTYL-1,2,4,5-TETRAPHOSPHA[2.2]PENTANE, (TBUP)2C(TBUP)2
TEBBE, KF
HEINLEIN, T
FEHER, M
ZEITSCHRIFT FUR KRISTALLOGRAPHIE, 1985, 172 (1-2): : 89 - 95
[42] Synthesis of the stannatetraphospholanes (tBuP)(4)SnR(2) (R=tBu,nBu, C6H5) and (tBuP)(4)Sn(Cl)nBu - Molecular and crystal structure of (tBuP)(4)Sn(tBu)(2)
Bongert, D
Hausen, HD
Schwarz, W
Heckmann, G
Binder, H
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1996, 622 (07): : 1167 - 1172
[43] 2,3,4,5-TETRAHYDRO-1H-PHOSPHORINO[4,3-B]INDOLES AND DERIVATIVES
SRIVASTAVA, KC
BERLIN, KD
JOURNAL OF ORGANIC CHEMISTRY, 1972, 37 (26): : 4487 - 4489
[44] 2,3,4,5-tetrahydro- and 2,3,4,5,11,11a-hexahydro-1H-[1,4]diazepino[1,7-a]indoles:: New templates for 5-HT2C agonists
Ennis, MD
Hoffman, RL
Ghazal, NB
Olson, RM
Knauer, CS
Chio, CL
Hyslop, DK
Campbell, JE
Fitzgerald, LW
Nichols, NF
Svensson, KA
McCall, RB
Haber, CL
Kagey, ML
Dinh, DM
BIOORGANIC & MEDICINAL CHEMISTRY LETTERS, 2003, 13 (14) : 2369 - 2372
[45] Tetramethyl 1,1,2-triphenyl-2H-1λ5-phosphole-2,3,4,5-tetracarboxylate
Krawczyk, Krzysztof K.
Wojtasiewicz, Krystyna
Maurin, Jan K.
Gronowska, Ewa
Czarnocki, Zbigniew
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2010, 66 : O2791 - U2373
[46] 2,2,4-Trimethyl-5-(4-tolylsulfonyl)-2,3,4,5-tetrahydro-1H-1,5-benzodiazepine
Ravichandran, K.
Sathiyaraj, K.
Ilango, S. S.
Ponnuswamy, S.
Ponnuswamy, M. N.
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2009, 65 : O2363 - +
[47] TOTAL SYNTHESIS AND ABSOLUTE-CONFIGURATION OF (+)-(1,2,3/4,5)-2,3,4,5-TETRAHYDROXY-1-CYCLOHEXANEMETHANOL
OGAWA, S
IWASAWA, Y
SUAMI, T
CHEMISTRY LETTERS, 1984, (03) : 355 - 356
[48] MASS-SPECTRA OF NEW "3,5-METHANO-2,3,4,5-TETRAHYDRO-1H-1 AND "3,5-METHANO-2,3,4,5-TETRAHYDRO-1H-2 BENZAZEPINES AND OXO DERIVATIVES
ESCALE, R
ELKHAYAT, A
VIDAL, JP
GIRARD, JP
ROSSI, JC
ORGANIC MASS SPECTROMETRY, 1986, 21 (06): : 379 - 380
[49] CRYSTAL-STRUCTURE AND CONFORMATION OF METHYL 2,3,4,5-TETRA-O-ACETYL-ALPHA-D-GLUCOSEPTANOSIDE
MCCONNEL.JF
STEVENS, JD
ACTA CRYSTALLOGRAPHICA A-FOUNDATION AND ADVANCES, 1972, 28 : S21 - S21
[50] Synthesis of 2-trifluoromethyl-2,3,4,5-tetrahydro-1H-3-benzazepine derivatives
Kawase, M
Niwa, M
Nozaki, M
Motohashi, N
HETEROCYCLES, 1998, 48 (03) : 555 - 560

← 1 2 3 4 5 →