1,1-diethyl-1-germa-2,3,4,5-tetra-tert-butyl-2,3,4,5-tetraphospholane (C2H5)2Ge(tBuP)4, molecular and crystal structure

被引：0

作者：

Binder, H ^{[1
]}

Schuster, B ^{[1
]}

Schwarz, W ^{[1
]}

Klinkhammer, KW ^{[1
]}

机构：

[1] Univ Stuttgart, Inst Anorgan Chem, D-70569 Stuttgart, Germany

来源：

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 1999年 / 625卷 / 05期

关键词：

1-germa-2,3,4,5-tetraphospholane; NMR data; crystal structure;

D O I：

10.1002/(SICI)1521-3749(199905)625:5<699::AID-ZAAC699>3.3.CO;2-H

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction of the diphosphide K-2[(tBuP)(4)] THF (1) with the germanium(IV) compound (C2H5)(2)GeCl2 leads via a [4 + 1]-cyclo-condensation reaction to 1,1-diethyl-1-germa-2,3,4,5-tetra-tert-butyl-2,3,4,5-tetraphospholane (C2H5)(2)Ge(tBuP)(4) (2) with the 5-membered GeP4 ring system. 2 could be characterized P-31 NMR spectroscopically, mass spectrometrically and by a single crystal structure analysis.

引用

页码：699 / 701

页数：3

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