1,1-diethyl-1-germa-2,3,4,5-tetra-tert-butyl-2,3,4,5-tetraphospholane (C2H5)2Ge(tBuP)4, molecular and crystal structure

被引：0
|
作者：
Binder, H [1 ]
Schuster, B [1 ]
Schwarz, W [1 ]
Klinkhammer, KW [1 ]
机构：
[1] Univ Stuttgart, Inst Anorgan Chem, D-70569 Stuttgart, Germany
来源：
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 1999年 / 625卷 / 05期
关键词：
1-germa-2,3,4,5-tetraphospholane; NMR data; crystal structure;
D O I：
10.1002/(SICI)1521-3749(199905)625:5<699::AID-ZAAC699>3.3.CO;2-H
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The reaction of the diphosphide K-2[(tBuP)(4)] THF (1) with the germanium(IV) compound (C2H5)(2)GeCl2 leads via a [4 + 1]-cyclo-condensation reaction to 1,1-diethyl-1-germa-2,3,4,5-tetra-tert-butyl-2,3,4,5-tetraphospholane (C2H5)(2)Ge(tBuP)(4) (2) with the 5-membered GeP4 ring system. 2 could be characterized P-31 NMR spectroscopically, mass spectrometrically and by a single crystal structure analysis.
引用
收藏
页码：699 / 701
页数：3
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