1,1-diethyl-1-germa-2,3,4,5-tetra-tert-butyl-2,3,4,5-tetraphospholane (C2H5)2Ge(tBuP)4, molecular and crystal structure

被引：0

作者：

Binder, H ^{[1
]}

Schuster, B ^{[1
]}

Schwarz, W ^{[1
]}

Klinkhammer, KW ^{[1
]}

机构：

[1] Univ Stuttgart, Inst Anorgan Chem, D-70569 Stuttgart, Germany

来源：

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 1999年 / 625卷 / 05期

关键词：

1-germa-2,3,4,5-tetraphospholane; NMR data; crystal structure;

D O I：

10.1002/(SICI)1521-3749(199905)625:5<699::AID-ZAAC699>3.3.CO;2-H

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction of the diphosphide K-2[(tBuP)(4)] THF (1) with the germanium(IV) compound (C2H5)(2)GeCl2 leads via a [4 + 1]-cyclo-condensation reaction to 1,1-diethyl-1-germa-2,3,4,5-tetra-tert-butyl-2,3,4,5-tetraphospholane (C2H5)(2)Ge(tBuP)(4) (2) with the 5-membered GeP4 ring system. 2 could be characterized P-31 NMR spectroscopically, mass spectrometrically and by a single crystal structure analysis.

引用

页码：699 / 701

页数：3

共 50 条

[1] ISOLABLE CYCLOBUTADIENES .6. 1,2,3,4-TETRA-TERT-BUTYLBEHZENE, 2,3,4,5-TETRA-TERT-BUTYLBIPHENYL, 2,3,4,5-TETRA-TERT-BUTLYLPYRIDINE, AND 2,3,4,5-TETRA-TERT-BUTYLFURAN
KREBS, A
FRANKEN, E
MULLER, S
TETRAHEDRON LETTERS, 1981, 22 (18) : 1675 - 1678
[2] 2,3,4,5-TETRAPHENYL-1,1-DIETHYNYL-1-GERMACYCLOPENTADIENE, C32H22GE
LINDEMAN, SV
SHKLOVER, VE
STRUCHKOV, YT
VASNYOVA, NA
SLADKOV, AM
CRYSTAL STRUCTURE COMMUNICATIONS, 1981, 10 (03): : 827 - 832
[3] Synthesis and structure of a series of oligo[1,1-(2,3,4,5,-tetramethylsilole)]s
Kanno, K
Ichinohe, M
Kabuto, C
Kira, M
CHEMISTRY LETTERS, 1998, (01) : 99 - 100
[4] Synthesis, properties, structure and reactivity of sodium 2,3,4,5-tetra-tert-butylcyclopentaphosphanide
Schisler, A
Lönnecke, P
Hey-Hawkins, H
PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS, 2002, 177 (6-7) : 1447 - 1450
[5] THE CRYSTAL-STRUCTURE OF 1,1-BIS(ETA-5-CYCLOPENTADIENYL)-2,3,4,5-TETRAPHENYLZIRCONOLE
HUNTER, WE
ATWOOD, JL
FACHINETTI, G
FLORIANI, C
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1981, 204 (01) : 67 - 74
[6] PYROLYSIS OF 2,3,4,5-TETRAPHENYLTHIOPHEN 1,1-DIOXIDE
MCOMIE, JFW
BULLIMOR.BK
CHEMICAL COMMUNICATIONS, 1965, (04) : 63 - &
[7] THE CRYSTAL-STRUCTURE OF 1,1-DIMETHYL-2,3,4,5-TETRAPHENYL-1-SILACYCLOPENTADIENE
PARKANYI, L
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1981, 216 (01) : 9 - 16
[8] 1-PHENETHYL-2,3,4,5-TETRAHYDRO-1H-2-BENZAZEPINES FROM 2-ACETYL-1-METHYLENE-2,3,4,5-TETRAHYDRO-1H-2-BENZAZEPINES
ALONSO, R
BROSSI, A
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1987, 194 : 64 - ORGN
[9] SUBSTITUTED "2,3,4,5-TETRAHYDRO-1H-3-BENZAZEPINE AND 2,3,4,5-TETRAHYDRO-1H-NAPHTH[1,2-D]AZEPINE DERIVATIVES
BOBOWSKI, G
GOTTLIEB, JM
WEST, B
SHAVEL, J
JOURNAL OF HETEROCYCLIC CHEMISTRY, 1979, 16 (08) : 1525 - 1534
[10] 1-PHENETHYL-2,3,4,5-TETRAHYDRO-1H-2-BENZAZEPINES FROM 2-ACETYL-1-METHYLENE-2,3,4,5-TETRAHYDRO-1H-2-BENZAZEPINES
ALONSO, R
BROSSI, A
HETEROCYCLES, 1987, 26 (08) : 2209 - 2213

← 1 2 3 4 5 →