Synthesis and Structure of Heterodinuclear Rhodium and Iridium Borylene Complexes

被引：12

作者：

Braunschweig, Holger ^{[1
]}

Forster, Melanie ^{[1
]}

Seeler, Fabian ^{[1
]}

机构：

[1] Univ Wurzburg, Inst Anorgan Chem, D-97074 Wurzburg, Germany

来源：

CHEMISTRY-A EUROPEAN JOURNAL | 2009年 / 15卷 / 02期

关键词：

boron; borylene complexes; bridging ligands; iridium; rhodium; TRANSITION-METAL-COMPLEXES; REACTION CHEMISTRY; THERMAL CONDITIONS; BRIDGING LIGAND; BORON; COORDINATION; REACTIVITY; ABSTRACTION; MONONUCLEAR; BASE;

D O I：

10.1002/chem.200801820

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Herein we report on the synthesis and structural characterization of a representative range of novel heterodinuclear bridging rhodium and iridium borylene complexes. The iridium borylene complexes feature an unusual coordination mode of the borylene ligand. Furthermore, the first instance of a heterodinuclear-bridged borylene compound containing a chromium atom in the three-membered ring is reported.

引用

下载

页码：469 / 473

页数：5

共 50 条

[21] NEW COMPLEXES OF RHODIUM(III) AND IRIDIUM(III) WITH THIAZOLE AND IMIDAZOLE DERIVATIVES - SYNTHESIS AND STRUCTURE
RONG, M
MUIR, MM
COX, O
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1989, 197 : 195 - INOR
[22] Synthesis, structure, and reactivity of bis(oxazoline)-substituted cyclopentadienyl and fluorenyl rhodium and iridium complexes
Schmidt, Bradley
Sadow, Aaron
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2015, 249
[23] SYNTHESIS AND STRUCTURE OF THE FIRST TRANSITION-METAL BORYLENE COMPLEXES
BRAUNSCHWEIG, H
WAGNER, T
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1995, 34 (07): : 825 - 826
[24] Synthesis, Structure, and Bonding of Bimetallic Bridging Borylene and Boryl Complexes
Saha, Koushik
Kar, Sourav
Kaur, Urminder
Roisnel, Thierry
Ghosh, Sundargopal
ORGANOMETALLICS, 2020, 39 (23) : 4362 - 4371
[25] HYDROTRIPYRAZOLYLBORATE COMPLEXES OF RHODIUM AND IRIDIUM
MAY, S
REINSALU, P
POWELL, J
INORGANIC CHEMISTRY, 1980, 19 (06) : 1582 - 1589
[26] Allenylphosphonium Complexes of Rhodium and Iridium
Cade, Ian A.
Colebatch, Annie L.
Hill, Anthony F.
Willis, Anthony C.
ORGANOMETALLICS, 2014, 33 (12) : 3198 - 3204
[27] TETRACYANOETHYLENE COMPLEXES OF RHODIUM AND IRIDIUM
BADDLEY, WH
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1966, 88 (19) : 4545 - &
[28] ACETYLENE COMPLEXES OF IRIDIUM AND RHODIUM
COLLMAN, JP
KANG, JW
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1967, 89 (04) : 844 - &
[29] Stepwise intermetal borylene transfer: Synthesis and structure of mono- and dinuclear cobalt-borylene complexes
Braunschweig, Holger
Forster, Melanie
Radacki, Krzysztof
Seeler, Fabian
Whittell, George R.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2007, 46 (27) : 5212 - 5214
[30] Dihydrogen Complexes of Iridium and Rhodium
Findlater, Michael
Schultz, Katherine M.
Bernskoetter, Wesley H.
Cartwright-Sykes, Alison
Heinekey, D. Michael
Brookhart, Maurice
INORGANIC CHEMISTRY, 2012, 51 (08) : 4672 - 4678

← 1 2 3 4 5 →