Synthesis and Structure of Heterodinuclear Rhodium and Iridium Borylene Complexes

被引：12

作者：

Braunschweig, Holger ^{[1
]}

Forster, Melanie ^{[1
]}

Seeler, Fabian ^{[1
]}

机构：

[1] Univ Wurzburg, Inst Anorgan Chem, D-97074 Wurzburg, Germany

来源：

CHEMISTRY-A EUROPEAN JOURNAL | 2009年 / 15卷 / 02期

关键词：

boron; borylene complexes; bridging ligands; iridium; rhodium; TRANSITION-METAL-COMPLEXES; REACTION CHEMISTRY; THERMAL CONDITIONS; BRIDGING LIGAND; BORON; COORDINATION; REACTIVITY; ABSTRACTION; MONONUCLEAR; BASE;

D O I：

10.1002/chem.200801820

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Herein we report on the synthesis and structural characterization of a representative range of novel heterodinuclear bridging rhodium and iridium borylene complexes. The iridium borylene complexes feature an unusual coordination mode of the borylene ligand. Furthermore, the first instance of a heterodinuclear-bridged borylene compound containing a chromium atom in the three-membered ring is reported.

引用

页码：469 / 473

页数：5

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