SYNTHESIS AND STRUCTURE OF THE FIRST TRANSITION-METAL BORYLENE COMPLEXES

被引：99
|
作者：
BRAUNSCHWEIG, H
WAGNER, T
机构：
[1] Institut Für Anorganische Chemie, Technischen Hochschule, Aachen
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1995年 / 34卷 / 07期
关键词：
BORON COMPOUNDS; COMPLEXES WITH BORON LIGANDS; MANGANESE COMPOUNDS;
D O I：
10.1002/anie.199508251
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The stable borylene‐bridged Mn2 complexes 1 and 2 are formed in the reaction of K[(η5‐C5H4R)‐Mn(SiMePh2)(CO)2] with the diboranes(4) B2X2Cl2. The mechanism of formation still remains to be clarified. The molecular structure of 1 (R = H) shows similarities with dimetallacyclopropane derivatives. (Figure Presented.) Copyright © 1995 by VCH Verlagsgesellschaft mbH, Germany
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页码：825 / 826
页数：2
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