One-Pot Synthesis of Polycyclic Spirooxindoles via Montmorillonite K10-Catalyzed C-H Functionalization of Cyclic Amines

被引：32
|
作者：
Zhang, Xiaofeng [1 ,2 ]
Liu, Miao [1 ,2 ]
Qiu, Weiqi [1 ,2 ]
Evans, Jason [1 ,2 ]
Kaur, Manpreet [3 ]
Jasinski, Jerry P. [3 ]
Zhang, Wei [1 ,2 ]
机构：
[1] Univ Massachusetts, Ctr Green Chem, 100 Morrissey Blvd, Boston, MA 02125 USA
[2] Univ Massachusetts, Dept Chem, 100 Morrissey Blvd, Boston, MA 02125 USA
[3] Keene State Coll, Dept Chem, 229 Main St, Keene, NH 03435 USA
来源：
ACS SUSTAINABLE CHEMISTRY & ENGINEERING | 2018年 / 6卷 / 04期
关键词：
3+2] Cycloaddition; Spirooxindoles; Montmorillonite K10; Heterogeneous catalysis; Recyclable; alpha-C-H functionalization; AZOMETHINE YLIDE ROUTE; DIASTEREOSELECTIVE SYNTHESIS; STEREOSELECTIVE-SYNTHESIS; ASYMMETRIC-SYNTHESIS; 3+2 CYCLOADDITION; REDOX; CATALYSIS; OXINDOLES; TRANSFORMATIONS; STEREOCENTERS;
D O I：
10.1021/acssuschemeng.8b00555
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A method for pot and atom economic synthesis of polycyclic spirooxindoles through alpha-C-H functionalization of cyclic amines has been developed. This highly efficient three-component [3+2] cycloaddition reaction was catalyzed by recyclable montmorillonite K10 and only water was produced as a byproduct.
引用
收藏
页码：5574 / 5579
页数：11
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