One-Pot Synthesis of Polycyclic Spirooxindoles via Montmorillonite K10-Catalyzed C-H Functionalization of Cyclic Amines

被引：32

作者：

Zhang, Xiaofeng ^{[1
,2
]}

Liu, Miao ^{[1
,2
]}

Qiu, Weiqi ^{[1
,2
]}

Evans, Jason ^{[1
,2
]}

Kaur, Manpreet ^{[3
]}

Jasinski, Jerry P. ^{[3
]}

Zhang, Wei ^{[1
,2
]}

机构：

[1] Univ Massachusetts, Ctr Green Chem, 100 Morrissey Blvd, Boston, MA 02125 USA

[2] Univ Massachusetts, Dept Chem, 100 Morrissey Blvd, Boston, MA 02125 USA

[3] Keene State Coll, Dept Chem, 229 Main St, Keene, NH 03435 USA

来源：

ACS SUSTAINABLE CHEMISTRY & ENGINEERING | 2018年 / 6卷 / 04期

关键词：

3+2] Cycloaddition; Spirooxindoles; Montmorillonite K10; Heterogeneous catalysis; Recyclable; alpha-C-H functionalization; AZOMETHINE YLIDE ROUTE; DIASTEREOSELECTIVE SYNTHESIS; STEREOSELECTIVE-SYNTHESIS; ASYMMETRIC-SYNTHESIS; 3+2 CYCLOADDITION; REDOX; CATALYSIS; OXINDOLES; TRANSFORMATIONS; STEREOCENTERS;

D O I：

10.1021/acssuschemeng.8b00555

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A method for pot and atom economic synthesis of polycyclic spirooxindoles through alpha-C-H functionalization of cyclic amines has been developed. This highly efficient three-component [3+2] cycloaddition reaction was catalyzed by recyclable montmorillonite K10 and only water was produced as a byproduct.

引用

页码：5574 / 5579

页数：11

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