Water as a regulator of catalytic activity of tetrabutoxy titanium in amide formation

被引：0
|
作者：
Shteinberg, LY [1 ]
Kondratov, SA
Shein, SM
Mishchenko, SE
Dolmat, VM
Dibrova, VM
机构：
[1] KRASITEL Publ Co, Inst Chem Technol & Ind Ecol, Rubezhnoe, Ukraine
[2] Inst Appl Chem, Rubezhnoe, Ukraine
[3] NPO Organ Intermediaries & Dyes NIOPIK, Moscow 103787, Russia
来源：
KINETICS AND CATALYSIS | 1999年 / 40卷 / 04期
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D O I：
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中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The interaction of tetrabutoxy titanium with water from a gas phase significantly changes its catalytic activity in the reaction of aniline with benzoic acid. Tetrabutoxy titanium reaction with water is studied by the H-1 NMR method, The concentration and possible structure of a complex having the maximum catalytic activity were determined. The probable mechanism of catalytic amide formation in the presence of tetrabutoxy titanium activated by water is discussed.
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页码：511 / 515
页数：5
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