Water as a regulator of catalytic activity of tetrabutoxy titanium in amide formation

被引：0
|
作者：
Shteinberg, LY [1 ]
Kondratov, SA
Shein, SM
Mishchenko, SE
Dolmat, VM
Dibrova, VM
机构：
[1] KRASITEL Publ Co, Inst Chem Technol & Ind Ecol, Rubezhnoe, Ukraine
[2] Inst Appl Chem, Rubezhnoe, Ukraine
[3] NPO Organ Intermediaries & Dyes NIOPIK, Moscow 103787, Russia
来源：
KINETICS AND CATALYSIS | 1999年 / 40卷 / 04期
关键词：
D O I：
暂无
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The interaction of tetrabutoxy titanium with water from a gas phase significantly changes its catalytic activity in the reaction of aniline with benzoic acid. Tetrabutoxy titanium reaction with water is studied by the H-1 NMR method, The concentration and possible structure of a complex having the maximum catalytic activity were determined. The probable mechanism of catalytic amide formation in the presence of tetrabutoxy titanium activated by water is discussed.
引用
收藏
页码：511 / 515
页数：5
相关论文
共 50 条
  • [31] OXIDE FILM FORMATION AND THICKENING ON TITANIUM IN WATER
    ELDIN, AMS
    HAMMOUD, AA
    THIN SOLID FILMS, 1988, 167 (1-2) : 269 - 280
  • [32] EFFECT OF WATER ON CATALYTIC ACTIVITY OF BIS(PI-CYCLOPENTADIENYL)TITANIUM DICHLORIDE DIMETHYLALUMINUM CHLORIDE FOR POLYMERIZATION OF ETHYLENE
    LONG, WP
    BRESLOW, DS
    ANNALEN DER CHEMIE-JUSTUS LIEBIG, 1975, (03): : 463 - 469
  • [33] Catalytic Carbanion Reactions: Formation and Reaction of Carbanions from Ester or Amide Equivalents Using Catalytic Amounts of Bases
    Kobayashi, Shu
    Matsubara, Ryosuke
    CHEMISTRY-A EUROPEAN JOURNAL, 2009, 15 (41) : 10694 - 10700
  • [34] Investigating Catalytic Effect of Titanium Dioxide on Solar Disinfection of Water
    Saleemi, Anwar Rashid
    Ramzan, Naveed
    Hafeez, Muhammad Naeem
    JOURNAL OF THE CHEMICAL SOCIETY OF PAKISTAN, 2009, 31 (01): : 26 - 30
  • [35] WATER ACTIVITY - A POSSIBLE EXTERNAL REGULATOR IN BIOTECHNICAL PROCESSES
    HAHNHAGERDAL, B
    ENZYME AND MICROBIAL TECHNOLOGY, 1986, 8 (06) : 322 - 327
  • [36] The synthesis, structure and catalytic activity of mono(salicylaldiminato) titanium complexes
    Pennington, DA
    Hughes, DL
    Bochmann, M
    Lancaster, SJ
    DALTON TRANSACTIONS, 2003, (18) : 3480 - 3482
  • [37] Recent studies on the catalytic activity of titanium, zirconium, and hafnium oxides
    Salem, I
    CATALYSIS REVIEWS-SCIENCE AND ENGINEERING, 2003, 45 (02): : 205 - 296
  • [38] CATALYTIC AND PHOTOCATALYTIC FORMATION OF OXYGEN FROM WATER
    SHAFIROVICH, VY
    SHILOV, AE
    KINETICS AND CATALYSIS, 1982, 23 (06) : 1110 - 1120
  • [39] Electrochemical hydrogenation prepares titanium with catalytic activity for electroless plating
    Xu, Lingli
    Tong, Xuqiang
    Pei, Honghao
    Yin, Long
    Cui, Yingjie
    Li, Boxuan
    Bang, Le Thi
    Shi, Xingling
    MATERIALS LETTERS, 2025, 384
  • [40] The study of properties and catalytic activity of titanium dioxide doped with sulphure
    Shvadchina, Yu. O.
    Cherepivskaya, M. K.
    Vakulenko, V. F.
    Sova, A. N.
    Stolyarova, I. V.
    Prikhodko, R. V.
    JOURNAL OF WATER CHEMISTRY AND TECHNOLOGY, 2015, 37 (06) : 283 - 288
12345