Controlling defects in crystalline carbon nitride to optimize photocatalytic CO2 reduction

被引:94
|
作者
Li, Han [1 ]
Zhu, Bicheng [1 ]
Cao, Shaowen [1 ]
Yu, Jiaguo [1 ]
机构
[1] Wuhan Univ Technol, State Key Lab Adv Technol Mat Synth & Proc, Wuhan 430070, Peoples R China
基金
中国国家自然科学基金;
关键词
SOLAR HYDROGEN-PRODUCTION; EXCITON DISSOCIATION; NANOSHEETS; EVOLUTION; G-C3N4;
D O I
10.1039/d0cc01338b
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The effective controlling of the defects of crystalline carbon nitride is presented. The rational strategy not only improves the crystallinity of carbon nitride, promoting the charge carrier transfer, but also introduces the nitrogen vacancies and cyano groups, serving as the optimal activation sites for enhanced CO2 reduction.
引用
收藏
页码:5641 / 5644
页数:4
相关论文
共 50 条
  • [21] Crystalline red phosphorus for selective photocatalytic reduction of CO2 into CO
    Hu, Zhuofeng
    Lu, Yinglong
    Liu, Minghao
    Zhang, Xiaoyue
    Cai, JunJie
    JOURNAL OF MATERIALS CHEMISTRY A, 2021, 9 (01) : 338 - 348
  • [22] Discovery of a Hybrid System for Photocatalytic CO2 Reduction via Attachment of a Molecular Cobalt-Quaterpyridine Complex to a Crystalline Carbon Nitride
    McGuigan, Scott
    Tereniak, Stephen J.
    Donley, Carrie L.
    Smith, Avery
    Jeon, Sungho
    Zhao, Fengyi
    Sampaio, Renato N.
    Pauly, Magnus
    Keller, Landon
    Collins, Leonard
    Parsons, Gregory N.
    Lian, Tianquan
    Stach, Eric A.
    Maggard, Paul A.
    ACS APPLIED ENERGY MATERIALS, 2023, 6 (20) : 10542 - 10553
  • [23] S-scheme heterojunction of crystalline carbon nitride nanosheets and ultrafine WO3 nanoparticles for photocatalytic CO2 reduction
    Chen, Gongjie
    Zhou, Ziruo
    Li, Bifang
    Lin, Xiahui
    Yang, Can
    Fang, Yuanxing
    Lin, Wei
    Hou, Yidong
    Zhang, Guigang
    Wang, Sibo
    JOURNAL OF ENVIRONMENTAL SCIENCES, 2024, 140 : 103 - 112
  • [24] Impact of transition metal incorporation on the photocatalytic CO2 reduction activity of polymeric carbon nitride
    Li, Jiahui
    Li, Keyan
    Du, Jun
    Yang, Hong
    Song, Chunshan
    Guo, Xinwen
    JOURNAL OF CO2 UTILIZATION, 2022, 64
  • [25] Construction of Carbon Nitride Based Intramolecular D–A System for Effective Photocatalytic Reduction of CO2
    Xinyu Zhang
    Xianghai Song
    Yongsheng Yan
    Pengwei Huo
    Catalysis Letters, 2022, 152 : 559 - 569
  • [26] Probing the effect of P-doping in polymeric carbon nitride on CO2 photocatalytic reduction
    Guo, Yangkun
    Wang, Min
    Tian, Jianjian
    Shen, Meng
    Zhang, Lingxia
    Shi, Jianlin
    DALTON TRANSACTIONS, 2020, 49 (44) : 15750 - 15757
  • [27] Synthesis of Carbon Nitride Nanosheets with n→π* Electronic Transition for Boosting Photocatalytic CO2 Reduction
    Song, Bing
    Zhang, Min
    Hou, Shiying
    Liang, Huirong
    Li, Qiuye
    Yang, Jianjun
    JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2023, 170 (03)
  • [28] Bioinspired Photocatalytic NADH Regeneration by Covalently Metalated Carbon Nitride for Enhanced CO2 Reduction
    Zhang, Yuanyuan
    Liu, Jian
    CHEMISTRY-A EUROPEAN JOURNAL, 2022, 28 (55)
  • [29] Facets and Defects in Perovskite Nanocrystals for Photocatalytic CO2 Reduction
    Shyamal, Sanjib
    Dutta, Sumit Kumar
    Das, Tisita
    Sen, Suvodeep
    Chakraborty, Sudip
    Pradhan, Narayan
    JOURNAL OF PHYSICAL CHEMISTRY LETTERS, 2020, 11 (09): : 3608 - 3614
  • [30] Selective Photocatalytic Reduction of CO2 to CO Mediated by Silver Single Atoms Anchored on Tubular Carbon Nitride
    Hu, Shan
    Qiao, Panzhe
    Yi, Xinli
    Lei, Yiming
    Hu, Huilin
    Ye, Jinhua
    Wang, Defa
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2023, 62 (26)