Ni-Catalyzed Formal Carbonyl-Ene Reaction of Terminal Alkenes via Carbon Dioxide Insertion

被引：13

作者：

Mori, Yasuyuki ^{[1
]}

Shigeno, Chieko ^{[2
]}

Luo, Ying ^{[2
]}

Chan, Bun ^{[2
]}

Onodera, Gen ^{[2
]}

Kimura, Masanari ^{[2
]}

机构：

[1] Kindai Univ, Mol Engn Inst, 11-6 Kayanomori Iizuka, Fukuoka 8208555, Japan

[2] Nagasaki Univ, Grad Sch Engn, Bunkyo Machi 1-14, Nagasaki 8528521, Japan

来源：

SYNLETT | 2018年 / 29卷 / 06期

基金：

日本学术振兴会;

关键词：

nickel catalyst; carbon dioxide; carbonyl-ene; ketone; organoaluminum; COUPLING REACTION; MULTICOMPONENT CONNECTION; TRIFLUOROMETHYL KETONES; COPPER(II) COMPLEXES; CONJUGATED ENYNE; NICKEL; ALDEHYDES; DIMETHYLZINC; HOMOALLYLATION; 1,3-BUTADIENE;

D O I：

10.1055/s-0036-1591845

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Nickel catalyzes the multicomponent coupling reaction of terminal alkenes, carbon dioxide, and organoaluminum reagents, leading to the synthesis of homoallylic alcohols in moderate-to-good yields with excellent regio- and stereoselectivities.

引用

页码：742 / 746

页数：5

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