CHIRAL TITANIUM COMPLEX-CATALYZED CARBONYL-ENE REACTION WITH GLYOXYLATE - REMARKABLE POSITIVE NONLINEAR EFFECT

被引：0
|
作者：
MIKAMI, K
TERADA, M
机构：
来源：
TETRAHEDRON | 1992年 / 48卷 / 27期
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暂无
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The enantioselective glyoxylate-ene reaction catalyzed by chiral titanium complex derived from partially resolved binaphthol (BINOL) is shown to exhibit a remarkable level of asymmetric amplification (positive nonlinear effect). Thus, the optical yield of the ene product significantly exceeds the enantio-purity of the chiral ligand (BINOL).
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页码：5671 / 5680
页数：10
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