Ni-Catalyzed Formal Carbonyl-Ene Reaction of Terminal Alkenes via Carbon Dioxide Insertion

被引：13
|
作者：
Mori, Yasuyuki [1 ]
Shigeno, Chieko [2 ]
Luo, Ying [2 ]
Chan, Bun [2 ]
Onodera, Gen [2 ]
Kimura, Masanari [2 ]
机构：
[1] Kindai Univ, Mol Engn Inst, 11-6 Kayanomori Iizuka, Fukuoka 8208555, Japan
[2] Nagasaki Univ, Grad Sch Engn, Bunkyo Machi 1-14, Nagasaki 8528521, Japan
来源：
SYNLETT | 2018年 / 29卷 / 06期
基金：
日本学术振兴会;
关键词：
nickel catalyst; carbon dioxide; carbonyl-ene; ketone; organoaluminum; COUPLING REACTION; MULTICOMPONENT CONNECTION; TRIFLUOROMETHYL KETONES; COPPER(II) COMPLEXES; CONJUGATED ENYNE; NICKEL; ALDEHYDES; DIMETHYLZINC; HOMOALLYLATION; 1,3-BUTADIENE;
D O I：
10.1055/s-0036-1591845
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Nickel catalyzes the multicomponent coupling reaction of terminal alkenes, carbon dioxide, and organoaluminum reagents, leading to the synthesis of homoallylic alcohols in moderate-to-good yields with excellent regio- and stereoselectivities.
引用
收藏
页码：742 / 746
页数：5
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