The first coordination polymers based on octahedral hexahydroxo rhenium cluster complexes [Re6Q8(OH)6]4- (Q = S, Se) and alkaline earth metal cations

被引：33
|
作者：
Mironov, YV
Fedorov, VE
Bang, HJ
Kim, SJ
机构：
[1] Russian Acad Sci, Nikolaev Inst Inorgan Chem, Siberian Branch, Novosibirsk 630090, Russia
[2] Ewha Womans Univ, Dept Chem, Seoul 120750, South Korea
来源：
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY | 2006年 / 03期
关键词：
rhenium; synthesis; luminescent properties; cluster compounds;
D O I：
10.1002/ejic.200500738
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Seven novel octahedral cluster compounds [(Mg(H2O)(5)}(2)-Re6S8(OH)(6)]center dot 6H(2)O (1), [[Ca(H2O)(3)}(2)Re6S8(OH)(6)] (2), [{Ca(H2O)(3)}(2)Re6Se8(OH)(6)] (3), [{Sr-2(H2O)(10)}Re6S8(OH)(6)]center dot 6H(2)O (4), [(Sr-2(H2O)(10)}Re6Se8(OH)(6)]center dot 6H(2)O (5), [{Ba-2(H2O)(8)}Re6S8(OH)(6)] (6), and [{Ba-2(H2O)(8)}Re6Se8(OH)(6)] (7) were prepared by the direct reaction of K-4[Re6S8(OH)(6)]center dot 8H(2)O and K-4[Re6Se8(OH)(6)]-8H(2)O with the cations of the elements of main group II. All compounds have been characterized by single crystal X-ray diffraction. Compound I has a discrete molecular structure, compounds 4 and 5 have a one-dimensional chain structure, and compounds 2, 3, 6, and 7 crystallize in two different types of two-dimensional layered structure. This sulfur containing series has been characterized by luminescent spectroscopy.
引用
收藏
页码：553 / 557
页数：5
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