Octahedral rhenium cluster complexes with organic ligands:: Synthesis, structure and properties of [Re6Q8(3,5-Me2PzH)6]Br2•2(3,5-Me2PzH) (Q=S, Se)

被引：45
|
作者：
Mironov, YV
Brylev, KA
Shestopalov, MA
Yarovoi, SS
Fedorov, VE
Spies, H
Pietzsch, HJ
Stephan, H
Geipel, G
Bernhard, G
Kraus, W
机构：
[1] Russian Acad Sci, Nikolaev Inst Inogan Chem, SB, Novosibirsk 630090, Russia
[2] Forschungszentrum Rossendorf EV, Inst Bioorgan & Radiopharmaceut Chem, D-01314 Dresden, Germany
[3] Forschungszentrum Rossendorf EV, Inst Radiochem, D-01314 Dresden, Germany
[4] Bundesanstalt Mat Forsch & Prufung, D-12489 Berlin, Germany
来源：
INORGANICA CHIMICA ACTA | 2006年 / 359卷 / 04期
基金：
俄罗斯基础研究基金会;
关键词：
synthesis; crystal structure; rhenium complexes; octahedral clusters; organic ligands;
D O I：
10.1016/j.ica.2005.08.012
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Two new octahedral cluster complexes - [Re6S8(3,5-Me(2)PzH)(6)]Br-2 center dot 2(3,5-Me(2)PzH) (1) and [Re6Se8(3,5-Me(2)PzH)(6)]Br-2 center dot 2(3,5-Me(2)PzH) (2), where 3,5-Me(2)PzH is 3,5-dimethylpyrazole, have been synthesized using reaction of rhenium chalcobromide complexes Cs-4[Re6S8Br6] center dot 2H(2)O and Cs-3[Re6Se8Br6] center dot H2O, respectively, with molten 3,5-dimethylpyrazole. Both compounds synthesized were characterized by X-ray single-crystal diffraction and chemical analysis, IR and luminescent spectra. (c) 2005 Elsevier B.V. All rights reserved.
引用
收藏
页码：1129 / 1134
页数：6
相关论文
共 50 条
  • [1] [Re6Q7O(3,5-Me2PzH)6]Br2•3,5-Me2PzH (Q = S, Se) -: New octahedral rhenium cluster complexes with organic ligands:: Original synthetic approach and unexpected ligand exchange in the cluster core
    Mironov, YV
    Shestopalov, MA
    Brylev, KA
    Yarovoi, SS
    Romanenko, GV
    Fedorov, VE
    Spies, H
    Pietzsch, HJ
    Stephan, H
    Geipel, G
    Bernhard, G
    Kraus, W
    [J]. EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2005, (04) : 657 - 661
  • [2] X-ray and electronic structure of the [ReCl3(pzH)2(PPh3)] and [ReCl3(3,5-Me2pzH)2(PPh3)] complexes
    Machura, B
    Jaworska, M
    Kruszynski, R
    [J]. POLYHEDRON, 2004, 23 (10) : 1819 - 1827
  • [3] Bis(3,5-dimethylpyrazol-1-ato) zirconium complexes as precursors for ethylene polymerisation upon activation with MAO:: Syntheses, characterisation and X-ray molecular structure of [Zr(η2-3,5-Me2PZ)2Cl2(η1-3,5-Me2PzH)2]•(3,5-Me2PzH) and [Zr(η2-3,5-Me2PZ)2(CH2Ph)2] (3,5-Me2PZ=3,5-dimethylpyrazol-1-ato)
    Sanz, Martial
    Mosquera, Marta E. G.
    Cuenca, Tomas
    Ramirez de Arellano, Carmen
    Schormann, Mark
    Bochmann, Manfred
    [J]. POLYHEDRON, 2007, 26 (18) : 5339 - 5348
  • [4] Crystal structure of bis[1-{(3,5-dimethyl-1H-pyrazol-1-yl)methyl}-3,5-dimethyl-1H-pyrazol-2-ium] hexachlorouranate(IV): [H2C(3,5-Me2pz)(3,5-Me2pzH)]2[UCl6]
    J. M. Carretas
    J. Cui
    A. Cruz
    I. C. Santos
    J. Marçalo
    [J]. Journal of Structural Chemistry, 2015, 56 : 181 - 185
  • [5] Crystal structure of bis[1-{(3,5-dimethyl-1H-pyrazol-1-yl)methyl}-3,5-dimethyl-1H-pyrazol-2-ium] hexachlorouranate(IV): [H2C(3,5-Me2pz)(3,5-Me2pzH)]2[UCl6]
    Carretas, J. M.
    Cui, J.
    Cruz, A.
    Santos, I. C.
    Marcalo, J.
    [J]. JOURNAL OF STRUCTURAL CHEMISTRY, 2015, 56 (01) : 181 - 185
  • [6] Octahedral hexahydroxo rhenium cluster complexes [Re6Q8(OH)6]4-•: (Q = S, Se):: Aynthesis, structure, and properties
    Yarovoi, SS
    Mironov, YV
    Naumov, DY
    Gatilov, YV
    Kozova, SG
    Kim, SJ
    Fedorov, VE
    [J]. EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2005, (19) : 3945 - 3949
  • [7] Chloro-lanthanide, and plutonium complexes containing the hydrotris(3,5-dimethylpyrazol-1-yl)borate ligand:: the crystal and molecular structures of [PrCl(μ-Cl)TpMe2(3,5-Me2pzH)]2 and YbCl2TpMe2(THF)
    Apostolidis, C
    Carvalho, A
    Domingos, A
    Kanellakopulos, B
    Maier, R
    Marques, N
    de Matos, AF
    Rebizant, J
    [J]. POLYHEDRON, 1998, 18 (1-2) : 263 - 272
  • [8] Synthesis, structure and luminescence properties of new chalcogenide octahedral rhenium cluster complexes with 4-aminopyridine [{Re6Q8}(4-NH2-py)6]2+
    Ivanov, Anton A.
    Khlestkin, Vadim K.
    Brylev, Konstantin A.
    Eltsov, Ilia V.
    Smolentsev, Anton I.
    Mironov, Yuri V.
    Shestopalov, Michael A.
    [J]. JOURNAL OF COORDINATION CHEMISTRY, 2016, 69 (05) : 841 - 850
  • [9] Electronic State of Rhenium Complexes with Octahedral Chalcocyanide Cluster Anions [Re6Q8(CN)6]3– (Q = S, Se, Te). EPR and Magnetic Susceptibility Studies
    T. V. Larina
    V. N. Ikorskii
    N. T. Vasenin
    V. F. Anufrienko
    N. G. Naumov
    E. V. Ostanina
    V. E. Fedorov
    [J]. Russian Journal of Coordination Chemistry, 2002, 28 : 554 - 556
  • [10] A family of octahedral rhenium cluster complexes trans-[{Re6Q8}(PPh3)4X2] (Q = S or Se, X = Cl, Br or I): Preparation and halide-dependent luminescence properties
    Ivanov, Anton A.
    Shestopalov, Michael A.
    Brylev, Konstantin A.
    Khlestkin, Vadim K.
    Mironov, Yuri V.
    [J]. POLYHEDRON, 2014, 81 : 634 - 638
12345