Exploring the Breadth of Terminal Ligands Coordinated in [Mo6X8]4+- and [Re6Q8]2+-Based Cluster Complexes

被引：10
|
作者：
Szczepura, Lisa F. [1 ]
Soto, Ernesto [1 ]
机构：
[1] Illinois State Univ, Dept Chem, Normal, IL 61761 USA
来源：
LIGATED TRANSITION METAL CLUSTERS IN SOLID-STATE CHEMISTRY: THE LEGACY OF MARCEL SERGENT | 2019年 / 180卷
关键词：
Cluster; Ligands; Molybdenum; Rhenium; Synthetic methodology; HEXANUCLEAR MOLYBDENUM CLUSTERS; STRUCTURAL-CHARACTERIZATION; PHOTOPHYSICAL PROPERTIES; CRYSTAL-STRUCTURES; BUILDING-BLOCKS; HEXAPYRIDINE CLUSTERS; DIMENSIONAL REDUCTION; ORGANOMETALLIC STARS; OCTAHEDRAL CLUSTERS; ORGANIC-LIGANDS;
D O I：
10.1007/430_2019_32
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
This survey provides an overview of the different types of terminal ligands incorporated into molybdenum halide and rhenium chalcogenide cluster complexes. While the incorporation of halide and pseudohalide ligands is prevalent with these systems, this article focuses on the coordination of other nitrogen-, oxygen-, sulfur-, and carbon-donor ligands. Emphasis has been placed on synthetic methodologies and the significance behind coordination of these ligands to discrete cluster complexes.
引用
收藏
页码：75 / 108
页数：34
相关论文
共 50 条
  • [1] Functionalization of [Re6Q8(CN)6]4- clusters by methylation of cyanide ligands
    Mikhaylov, Maksim A.
    Mironova, Alina D.
    Brylev, Konstantin A.
    Sukhikh, Taisiya S.
    Eltsov, Ilia, V
    Stass, Dmitri, V
    Gushchin, Artem L.
    Kitamura, Noboru
    Sokolov, Maxim N.
    [J]. NEW JOURNAL OF CHEMISTRY, 2019, 43 (41) : 16338 - 16348
  • [2] IR SPECTROSCOPIC IDENTIFICATION OF CLUSTER GROUP [MO6X8]
    FEDOROV, VE
    KIRIK, SD
    [J]. JOURNAL OF STRUCTURAL CHEMISTRY, 1976, 17 (06) : 891 - 896
  • [3] PROPIOLATE CLUSTER COMPLEXES (Bu4N)2[Mo6X8(OOC-CCH)6] (X= Br, I)
    Mikhailov, M. A.
    Berezin, A. S.
    Sukhikh, T. S.
    Sheven', D. G.
    Gushchin, A. L.
    Sokolov, M. N.
    [J]. JOURNAL OF STRUCTURAL CHEMISTRY, 2021, 62 (12) : 1896 - 1906
  • [4] PROPIOLATE CLUSTER COMPLEXES (Bu4N)2[Mo6X8(OOC–C≡CH)6] (X = Br, I)
    M. A. Mikhailov
    A. S. Berezin
    T. S. Sukhikh
    D. G. Sheven’
    A. L. Gushchin
    M. N. Sokolov
    [J]. Journal of Structural Chemistry, 2021, 62 : 1896 - 1906
  • [5] Novel crystal structures of potassium salts of chalcohydroxo cluster complexes [Re6Q8(OH)6]4− (Q = S or Se)
    K. A. Brylev
    [J]. Journal of Structural Chemistry, 2013, 54 : 196 - 200
  • [6] Novel crystal structures of potassium salts of chalcohydroxo cluster complexes [Re6Q8(OH)6]4- (Q = S or Se)
    Brylev, K. A.
    [J]. JOURNAL OF STRUCTURAL CHEMISTRY, 2013, 54 (01) : 196 - 200
  • [7] Octahedral hexahydroxo rhenium cluster complexes [Re6Q8(OH)6]4-•: (Q = S, Se):: Aynthesis, structure, and properties
    Yarovoi, SS
    Mironov, YV
    Naumov, DY
    Gatilov, YV
    Kozova, SG
    Kim, SJ
    Fedorov, VE
    [J]. EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2005, (19) : 3945 - 3949
  • [8] A theoretical study on [W6Q8(CN)6](6-) and [Re6Q8(CN)6](4-), Q = S, Se, cluster ions.
    Arratia-Perez, R
    Hernandez-Acevedo, L
    [J]. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2002, 223 : A54 - A54
  • [9] Mesolamellar phases containing [Re6Q8(CN)6]4- (Q = Te, Se, S) cluster anions
    Suh, Min-Jung
    Vien, Vo
    Huh, Seong
    Kim, Youngmee
    Kim, Sung-Jin
    [J]. EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2008, (05) : 686 - 692
  • [10] The first coordination polymers based on octahedral hexahydroxo rhenium cluster complexes [Re6Q8(OH)6]4- (Q = S, Se) and alkaline earth metal cations
    Mironov, YV
    Fedorov, VE
    Bang, HJ
    Kim, SJ
    [J]. EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2006, (03) : 553 - 557
12345