Enantioselective Hydrosilylation of Aromatic Alkenes Catalyzed by Chiral Bis(oxazolinyl)phenyl-Rhodium Acetate Complexes

被引：22

作者：

Naito, Tatsuo ^{[1
]}

Yoneda, Takuma ^{[1
]}

Ito, Jun-ichi ^{[1
]}

Nishiyama, Hisao ^{[1
]}

机构：

[1] Nagoya Univ, Grad Sch Engn, Dept Appl Chem, Chikusa Ku, Nagoya, Aichi 4648603, Japan

来源：

SYNLETT | 2012年 / 20期

基金：

日本学术振兴会;

关键词：

asymmetric hydrosilylation; alkene; bis(oxazolinyl)phenyl; rhodium; hydrosilane; ORGANIC-SYNTHESIS; ASYMMETRIC HYDROSILYLATION; SILAFUNCTIONAL COMPOUNDS; SILICON; HYDROBORATION; CARBON; MECHANISM; HYDROSILATION; PLATINUM(II); OXIDATION;

D O I：

10.1055/s-0032-1317677

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Highly efficient and enantioselective hydrosilylation of aromatic alkenes catalyzed by the chiral rhodium acetate complexes with the bis(oxazolinyl)phenyl ligands has been reported that afforded chiral silane derivatives with up to 99% ee.

引用

页码：2957 / 2960

页数：4

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