Catalytic enantioselective allylic oxidation of olefins with copper complexes of chiral nonracemic bis(oxazolinyl)pyridine type ligands

被引：83

作者：

DattaGupta, A ^{[1
]}

Singh, VK ^{[1
]}

机构：

[1] INDIAN INST TECHNOL,DEPT CHEM,KANPUR 208016,UTTAR PRADESH,INDIA

来源：

TETRAHEDRON LETTERS | 1996年 / 37卷 / 15期

关键词：

D O I：

10.1016/0040-4039(96)00347-4

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Olefins, on treatment with tert-butyl perbenzoate in the presence of a catalytic amount of chiral copper bis(oxazolinyl)pyridine complexes, gave optically active allylic benzoates. A variety of cyclic olefins were tried in the reaction and a maximum of 81% ee was obtained during this asymmetric oxidation reaction. Copyright (C) 1996 Elsevier Science Ltd

引用

页码：2633 / 2636

页数：4

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