Enantioselective palladium catalyzed allylic substitution with chiral pyridine ligands

被引：36
|
作者：
Chelucci, G [1 ]
Caria, V [1 ]
Saba, A [1 ]
机构：
[1] Univ Sassari, Dipartimento Chim, I-07100 Sassari, Italy
来源：
JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL | 1998年 / 130卷 / 1-2期
关键词：
palladium; allylic substitution; catalysis; enantioselectivity;
D O I：
10.1016/S1381-1169(97)00196-9
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Palladium complexes prepared in situ from [Pd(eta(3)-C3H5)Cl](2) and a number of chiral ligands with pyridine sp(2)-nitrogen donators were assessed as chiral catalysts for the allylic alkylation of 1,3-diphenylprop-2-enyl acetate with dimethyl malonate. Enantioselectivity of up to 64% was obtained. (C) 1998 Elsevier Science B.V.
引用
收藏
页码：51 / 55
页数：5
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