Enantioselective Hydrosilylation of Aromatic Alkenes Catalyzed by Chiral Bis(oxazolinyl)phenyl-Rhodium Acetate Complexes

被引：22
|
作者：
Naito, Tatsuo [1 ]
Yoneda, Takuma [1 ]
Ito, Jun-ichi [1 ]
Nishiyama, Hisao [1 ]
机构：
[1] Nagoya Univ, Grad Sch Engn, Dept Appl Chem, Chikusa Ku, Nagoya, Aichi 4648603, Japan
来源：
SYNLETT | 2012年 / 20期
基金：
日本学术振兴会;
关键词：
asymmetric hydrosilylation; alkene; bis(oxazolinyl)phenyl; rhodium; hydrosilane; ORGANIC-SYNTHESIS; ASYMMETRIC HYDROSILYLATION; SILAFUNCTIONAL COMPOUNDS; SILICON; HYDROBORATION; CARBON; MECHANISM; HYDROSILATION; PLATINUM(II); OXIDATION;
D O I：
10.1055/s-0032-1317677
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Highly efficient and enantioselective hydrosilylation of aromatic alkenes catalyzed by the chiral rhodium acetate complexes with the bis(oxazolinyl)phenyl ligands has been reported that afforded chiral silane derivatives with up to 99% ee.
引用
收藏
页码：2957 / 2960
页数：4
相关论文
共 50 条
  • [21] Rhodium-Catalyzed Asymmetric Hydrosilylation of Ketones Employing a New Ligand Embodying the Bis(oxazolinyl)pyridine Moiety
    Ghoshal, Atanu
    Sarkar, Asit R.
    Manickam, Govindaswamy
    Kumaran, R. Senthil
    Jayashankaran, J.
    SYNLETT, 2010, (10) : 1459 - 1462
  • [22] A study on chiral organocalcium complexes: Attempts in enantioselective catalytic hydrosilylation and intramolecular hydroamination of alkenes
    Buch, Frank
    Harder, Sjoerd
    ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 2008, 63 (02): : 169 - 177
  • [23] Carbon-hydrogen bond activation of arenes by a [bis(oxazolinyl)phenyl]rhodium(III) acetate complex
    Ito, Jun-ichi
    Nishiyama, Hisao
    EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2007, (08) : 1114 - 1119
  • [24] Chiral bis(oxazolinyl)phenylrhodium(III) complexes as Lewis acid catalysts for enantioselective allylation of aldehydes
    Motoyama, Y
    Narusawa, H
    Nishiyama, H
    CHEMICAL COMMUNICATIONS, 1999, (02) : 131 - 132
  • [25] Enantioselective rhodium catalyzed hydroboration of olefins using chiral bis(aminophosphine) ligands
    Brunel, JM
    Buono, G
    TETRAHEDRON LETTERS, 1999, 40 (18) : 3561 - 3564
  • [26] Enantioselective hydrosilylation of prochiral ketones catalyzed by chiral BINAP-copper(I) complexes
    Issenhuth, Jean-Thomas
    Dagorne, Samuel
    Bellemin-Laponnaz, Stephane
    COMPTES RENDUS CHIMIE, 2010, 13 (03) : 353 - 357
  • [27] Enantioselective cyclization/hydrosilylation of 1,6-enynes catalyzed by a cationic rhodium bis(phosphine) complex
    Chakrapani, H
    Liu, C
    Widenhoefer, RA
    ORGANIC LETTERS, 2003, 5 (02) : 157 - 159
  • [28] Enantioselective hydrogenation of enamides catalyzed by chiral rhodium-monodentate phosphite complexes
    Reetz, MT
    Mehler, G
    Meiswinkel, A
    Sell, T
    TETRAHEDRON LETTERS, 2002, 43 (44) : 7941 - 7943
  • [29] Enantioselective Addition of Allyltin Reagents to Amino Aldehydes Catalyzed with Bis(oxazolinyl)phenylrhodium(III) Aqua Complexes
    Motoyama, Yukihiro
    Sakakura, Takatoshi
    Takemoto, Toshihide
    Shimozono, Kayoko
    Aoki, Katsuyuki
    Nishiyama, Hisao
    MOLECULES, 2011, 16 (07) : 5387 - 5401
  • [30] Chiral Bis(Oxazolinyl)thiophenes for Enantioselective Cu(II)-Catalyzed Friedel–Crafts Alkylation of Indole Derivatives with Nitroalkenes
    Weijie Li
    Catalysis Letters, 2014, 144 : 943 - 948
12345