Copper(II) bis [2-((E)-2-(pyrid-2-yl)ethylimino)methyl)-6-bromo-4-chlorophenolate]

被引：1
|
作者：
Zhang, X. L. [1 ]
机构：
[1] Baoji Univ Arts & Sci, Dept Chem & Chem Engn, Baoji 721007, Shaanxi, Peoples R China
来源：
CRYSTALLOGRAPHY REPORTS | 2013年 / 58卷 / 01期
关键词：
Compendex;
D O I：
10.1134/S1063774513010318
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
A new complex CuL (2) [HL = 2-((E)-(2-(pyridin-2-yl)ethylimino)methyl)-6-bromo-4-chlorophenol] was synthesized, and its structure (C28H22Br2Cl2CuN4O2, Mr = 740.76) was determined by single-crystal X-ray diffraction analysis. The crystal belongs to the triclinic system, space group , with a = 5.157(6), b = 12.090(1), c =12.310(1) , alpha = 113.962(2)A degrees, beta = 96.7910(10)A degrees, gamma = 90.0300(10)A degrees, V = 695.4(8) (3), Z = 1, R = 0.0481. The complex molecules are linked via the weak C-H...N hydrogen bonds, leading to the formation of one dimension (1D) chains along the a axis.
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收藏
页码：119 / 121
页数：3
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