Copper(II) bis [2-((E)-2-(pyrid-2-yl)ethylimino)methyl)-6-bromo-4-chlorophenolate]

被引：1
|
作者：
Zhang, X. L. [1 ]
机构：
[1] Baoji Univ Arts & Sci, Dept Chem & Chem Engn, Baoji 721007, Shaanxi, Peoples R China
来源：
CRYSTALLOGRAPHY REPORTS | 2013年 / 58卷 / 01期
关键词：
Compendex;
D O I：
10.1134/S1063774513010318
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
A new complex CuL (2) [HL = 2-((E)-(2-(pyridin-2-yl)ethylimino)methyl)-6-bromo-4-chlorophenol] was synthesized, and its structure (C28H22Br2Cl2CuN4O2, Mr = 740.76) was determined by single-crystal X-ray diffraction analysis. The crystal belongs to the triclinic system, space group , with a = 5.157(6), b = 12.090(1), c =12.310(1) , alpha = 113.962(2)A degrees, beta = 96.7910(10)A degrees, gamma = 90.0300(10)A degrees, V = 695.4(8) (3), Z = 1, R = 0.0481. The complex molecules are linked via the weak C-H...N hydrogen bonds, leading to the formation of one dimension (1D) chains along the a axis.
引用
收藏
页码：119 / 121
页数：3
相关论文
共 50 条
  • [41] (E)-Methyl 2-[(4-bromo-2-formylphenoxy)methyl]-3-phenylacrylate
    Anuradha, T.
    Sivakumar, G.
    Seshadri, P. R.
    Bakthadoss, M.
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2011, 67 : O3322 - U505
  • [42] Bis{μ-2-[(pyridin-2-yl)iminomethyl]phenolato}bis[(2-formylphenolato)copper(II)]
    Chang, Hui-Chang
    Cole, Jacqueline M.
    Lin, Tze-Chia
    Sylvester, Sven O.
    Waddell, Paul G.
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2011, 67 : M690 - U490
  • [43] (E)-2-(2H-Benzotriazol-2-yl)-4-methyl-6-(phenyliminomethyl)phenol
    Li, Chi-Huan
    Su, Jing-Kai
    Li, Chen-Yu
    Ko, Bao-Tsan
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2010, 66 : O2825 - U254
  • [44] Synthesis, characterization, and antimicrobial activities of a dinuclear copper(II) complex with bis(2-[(2-hydroxy-ethylimino)-methyl]-4,6-diiodo-phenol)
    Huang, Xian-Feng
    Zhang, Yan-Bin
    Wang, Xiao-Liang
    Tang, Jian-Feng
    Ruan, Ban-Feng
    JOURNAL OF COORDINATION CHEMISTRY, 2011, 64 (04) : 630 - 636
  • [45] Syntheses, Characterization, Crystal Structures and Antimicrobial Activity of Schiff Base Copper(II) Complexes Derived from 2-Bromo-6-((2-(isopropylamino) ethylimino)methyl)phenol
    Yuan, Yong
    Lu, Xi-Kun
    Zhou, Gao-Qi
    Qiu, Xiao-Yang
    ACTA CHIMICA SLOVENICA, 2021, 68 (04) : 1008 - 1015
  • [46] Stereoselective synthesis of (E)-N,N-diethyl-3-(imidazo[1,2-a]pyrid-2-yl)-2-(phenylsulfonyl)propenamide
    Céard, S
    Roche, D
    Gaumet, V
    Gardette, D
    Métin, J
    Madesclaire, M
    JOURNAL OF MOLECULAR STRUCTURE, 2002, 608 (01) : 27 - 33
  • [47] [2-(2-{Bis[2-(1H-imidazol-2-ylmethyl-eneamino)ethyl] amino} ethylimino-methyl) imidazolido] cobalt(III) bis(tetrafluoridoborate) monohydrate
    Maria Atria, Ana
    Corsini, Gino
    Talamilla, Arlyn
    Teresa Garland, Maria
    Baggio, Ricardo
    ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY, 2008, 64 : M387 - M389
  • [48] BIS(2-(ETHYLIMINO-KAPPA-N-METHYL)-5-(HEXYLOXYPHENOXYCARBONYL)PHENOLATO-KAPPA-0)COPPER(II)
    CAROTENUTO, M
    IANNELLI, P
    IMMIRZI, A
    CARUSO, U
    ROVIELLO, A
    SIRIGU, A
    ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1990, 46 : 2031 - 2033
  • [49] COMPLEXES OF 3-AMINO(PYRID-2-YL)THIOUREA WITH COPPER(II), COBALT(II) AND NICKEL(II)
    PATEL, RK
    PATEL, RN
    JOURNAL OF THE INDIAN CHEMICAL SOCIETY, 1990, 67 (07) : 538 - 540
  • [50] (E)-6-Bromo-3-{2-[2-(4-chlorobenzylidene)hydrazinyl]thiazol-5-yl}-2H-chromen-2-one
    Arshad, Afsheen
    Osman, Hasnah
    Lam, Chan Kit
    Hemamalini, Madhukar
    Fun, Hoong-Kun
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2011, 67 : O1007 - U1675
12345