Di-μ1,1-azido-bis[(2-{1-[2-(isopropylamino)ethylimino]ethyl}phenolato)copper(II)]

被引：3
|
作者：
Li, He-Bing [1 ]
机构：
[1] Xiangnan Univ, Dept Chem & Life Sci, Chenzhou 423000, Peoples R China
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2010年 / 66卷
关键词：
MAGNETIC-PROPERTIES; STRUCTURAL-CHARACTERIZATION; AZIDO; COMPLEXES; BRIDGES;
D O I：
10.1107/S1600536810017174
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
In the centrosymmetric binuclear title complex, [Cu-2(C13H19N2O)(2)(N-3)(2)], the Cu-II atom adopts an elongated CuON4 square-based pyramidal coordination geometry, arising from the N,N',O-tridentate ligand and two bridging end-on azide anions. The O atom is in the basal plane, one of the azide N atoms is in the apical site and the Cu center dot center dot center dot Cu separation is 3.2365 (3) angstrom. A pair of intramolecular N-H center dot center dot center dot O hydrogen bonds helps to establish the molecular conformation.
引用
收藏
页码：M651 / U529
页数：11
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