One-pot SmI2-promoted transformation of carbohydrate derivatives into cyclopentanols

被引:0
|
作者
Grove, JJC [1 ]
Holzapfel, CW [1 ]
Williams, DBG [1 ]
机构
[1] RAND AFRIKAANS UNIV,DEPT CHEM & BIOCHEM,ZA-2006 AUCKLAND PARK,SOUTH AFRICA
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D O I
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中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Selectively functionalised carbohydrate derivatives underwent SmI2-promoted Grob-fragmentation reactions. This was followed by an in situ, stereocontrolled SmI2-mediated cyclisation to afford the corresponding cyclopentanols. Copyright (C) 1996 Published by Elsevier Science Ltd
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页码:5817 / 5820
页数:4
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