Hydrogen diazide -: Synthesis and crystal structure of PPh4[N3HN3]

被引：0
|
作者：
Neumüller, B [1 ]
Schmock, F [1 ]
Dehnicke, K [1 ]
机构：
[1] Univ Marburg, Fac Chem, D-35032 Marburg, Germany
来源：
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 1999年 / 625卷 / 08期
关键词：
hydrogen diazide; crystal structure;
D O I：
10.1002/(SICI)1521-3749(199908)625:8<1243::AID-ZAAC1243>3.0.CO;2-N
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
PPh4[N3HN3] has been prepared from PPh4N3 and Me3SiN3 by the reaction with water or ethanol forming colourless nonexplosive crystal needles, which were characterized by IR spectroscopy and by a crystal structure determination. Space group C2/c, Z = 12, lattice dimensions at -70 degrees C: a = 3782.4(3), b = 727.8(2), c = 2512.4(2) pm, beta = 110.13(1)degrees, R = 0.0841. The [N3HN3](-) ion is characterized by an asymmetric N-H ... N hydrogen bridge with a NN distance of 272(1) pm.
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收藏
页码：1243 / 1245
页数：3
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