Hydrogen diazide -: Synthesis and crystal structure of PPh4[N3HN3]

被引：0

作者：

Neumüller, B ^{[1
]}

Schmock, F ^{[1
]}

Dehnicke, K ^{[1
]}

机构：

[1] Univ Marburg, Fac Chem, D-35032 Marburg, Germany

来源：

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 1999年 / 625卷 / 08期

关键词：

hydrogen diazide; crystal structure;

D O I：

10.1002/(SICI)1521-3749(199908)625:8<1243::AID-ZAAC1243>3.0.CO;2-N

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

PPh4[N3HN3] has been prepared from PPh4N3 and Me3SiN3 by the reaction with water or ethanol forming colourless nonexplosive crystal needles, which were characterized by IR spectroscopy and by a crystal structure determination. Space group C2/c, Z = 12, lattice dimensions at -70 degrees C: a = 3782.4(3), b = 727.8(2), c = 2512.4(2) pm, beta = 110.13(1)degrees, R = 0.0841. The [N3HN3](-) ion is characterized by an asymmetric N-H ... N hydrogen bridge with a NN distance of 272(1) pm.

引用

页码：1243 / 1245

页数：3

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