Hydrogen diazide -: Synthesis and crystal structure of PPh4[N3HN3]

被引：0
|
作者：
Neumüller, B [1 ]
Schmock, F [1 ]
Dehnicke, K [1 ]
机构：
[1] Univ Marburg, Fac Chem, D-35032 Marburg, Germany
来源：
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 1999年 / 625卷 / 08期
关键词：
hydrogen diazide; crystal structure;
D O I：
10.1002/(SICI)1521-3749(199908)625:8<1243::AID-ZAAC1243>3.0.CO;2-N
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
PPh4[N3HN3] has been prepared from PPh4N3 and Me3SiN3 by the reaction with water or ethanol forming colourless nonexplosive crystal needles, which were characterized by IR spectroscopy and by a crystal structure determination. Space group C2/c, Z = 12, lattice dimensions at -70 degrees C: a = 3782.4(3), b = 727.8(2), c = 2512.4(2) pm, beta = 110.13(1)degrees, R = 0.0841. The [N3HN3](-) ion is characterized by an asymmetric N-H ... N hydrogen bridge with a NN distance of 272(1) pm.
引用
收藏
页码：1243 / 1245
页数：3
相关论文
共 50 条
  • [31] SYNTHESIS AND CRYSTAL-STRUCTURES OF (PPH4)2SE5 AND (PPH4)2[PD(SE4)2]
    KRAUTER, G
    DEHNICKE, K
    CHEMIKER-ZEITUNG, 1990, 114 (01): : 7 - 9
  • [32] SYNTHESIS AND CRYSTAL-STRUCTURE OF (PPH4)2[MO2CL10]
    HEY, E
    WELLER, F
    DEHNICKE, K
    ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1984, 508 (01): : 86 - 92
  • [33] TETRAPHENYLPHOSPHONIUM TETRAIODOTRITHIOTRIARSENATE, PPH4[AS3S3I4]
    SINNING, H
    MULLER, U
    ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1989, 568 (01): : 49 - 54
  • [34] (PPH4)2[OSCL3(NO)(SNCL3)2] - PREPARATION, IR-SPECTRUM, AND CRYSTAL-STRUCTURE
    CZESKA, B
    WELLER, F
    DEHNICKE, K
    ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1983, 498 (03): : 121 - 127
  • [35] Synthesis and crystal structure of [NEt4][CoCl3(PPh3)]
    Li, GQ
    Zheng, FK
    Guo, GC
    Huang, JS
    CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2000, 19 (03) : 230 - 233
  • [36] SYNTHESES, CRYSTAL-STRUCTURES AND PROPERTIES OF [PPH4]2[SBFE3H(CO)12] AND [PPH4]2[ASFE3H(CO)12]
    HENDERSON, P
    ROSSIGNOLI, M
    BURNS, RC
    SCUDDER, ML
    CRAIG, DC
    JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1994, (11): : 1641 - 1647
  • [37] THE CRYSTAL-STRUCTURES OF (PPH4)2[TICL3(NSIME3)]2.CH3CN AND (PPH4)2[TICL4(OSPCL2)]2
    WOLLERT, R
    WOCADLO, S
    DEHNICKE, K
    GOESMANN, H
    FENSKE, D
    ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 1992, 47 (10): : 1386 - 1392
  • [38] Synthesis and crystal structure determination of [PPh4][WO2S2(CuPPh3)] and of [Et4N]2[WS4(CuNCSe)4] with a sheet polymeric anion.: Synthesis and characterisation of [PPh4]2[WO2S2(CuNCS)]
    Beheshti, A
    Clegg, W
    Fallah, H
    INORGANICA CHIMICA ACTA, 2001, 322 (1-2) : 1 - 6
  • [39] SYNTHESIS AND CRYSTAL-STRUCTURE OF PPH4[REF2CL2(N2S2)]
    VOGLER, S
    DEHNICKE, K
    HILLER, W
    ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 1989, 44 (12): : 1509 - 1512
  • [40] AZIDO COMPLEXES OF ZIRCONIUM - ZRCL3N3, [ZRCL4N3]22-, [ZRCL4(N3)2]2- - CRYSTAL-STRUCTURE OF (PPH4)2 [ZRCL4N3]2
    DYCK, WM
    DEHNICKE, K
    BEYENDORFFGULBA, G
    STRAHLE, J
    ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1981, 482 (11): : 113 - 120
12345