Synthesis and crystal structure of 3-ammoniumphenyl sulfone selenate, 3-aminophenyl sulfone [C12H14N2O2S]SeO4 • [C12H12N2O2S]

被引：7

作者：

Mahroug, A. ^{[1
]}

Belhouchet, M. ^{[1
]}

Mhiri, T. ^{[1
]}

机构：

[1] Univ Sfax, Fac Sci Sfax, Dept Chim, Lab Physicochim Etat Solide, Sfax 3018, Tunisia

来源：

CRYSTALLOGRAPHY REPORTS | 2013年 / 58卷 / 04期

关键词：

NONLINEAR-OPTICAL PROPERTIES; ACID;

D O I：

10.1134/S1063774513040263

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The crystal structure of [C12H14N2O2S]SeO4 center dot [C12H12N2O2S] was determined by X-ray diffraction on single crystal. Crystals are orthorhombic, space group Pbca, with cell parameters a = 11.545 (1), b = 8.143 (1), c = 55.783(1), V = 5244.2 (8)(3) and Z = 8. The structure can be described as organic layers built by [C12H14N2O2S](2+) cations and [C12H12N2O2S] molecules, parallel to ab plane, between which the inorganic groups SeO (4) (2-) are inserted. In this atomic arrangement, H-bonds between the different species play an important role in the three-dimensional network cohesion.

引用

页码：613 / 616

页数：4

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