Synthesis and crystal structure of 3-ammoniumphenyl sulfone selenate, 3-aminophenyl sulfone [C12H14N2O2S]SeO4 • [C12H12N2O2S]

被引：7
|
作者：
Mahroug, A. [1 ]
Belhouchet, M. [1 ]
Mhiri, T. [1 ]
机构：
[1] Univ Sfax, Fac Sci Sfax, Dept Chim, Lab Physicochim Etat Solide, Sfax 3018, Tunisia
来源：
CRYSTALLOGRAPHY REPORTS | 2013年 / 58卷 / 04期
关键词：
NONLINEAR-OPTICAL PROPERTIES; ACID;
D O I：
10.1134/S1063774513040263
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
The crystal structure of [C12H14N2O2S]SeO4 center dot [C12H12N2O2S] was determined by X-ray diffraction on single crystal. Crystals are orthorhombic, space group Pbca, with cell parameters a = 11.545 (1), b = 8.143 (1), c = 55.783(1), V = 5244.2 (8)(3) and Z = 8. The structure can be described as organic layers built by [C12H14N2O2S](2+) cations and [C12H12N2O2S] molecules, parallel to ab plane, between which the inorganic groups SeO (4) (2-) are inserted. In this atomic arrangement, H-bonds between the different species play an important role in the three-dimensional network cohesion.
引用
收藏
页码：613 / 616
页数：4
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