Rh(III)-catalyzed synthesis of isoquinolines fromN-hydroxyoximes and alkynes inγ-valerolactone

被引：3
|
作者：
Jiang, Kuan-Chang [1 ]
Wang, Liang [1 ,2 ]
Chen, Qun [1 ]
He, Ming-Yang [1 ]
Shen, Ming-Gui [3 ]
Zhang, Zhi-Hui [1 ]
机构：
[1] Changzhou Univ, Jiangsu Key Lab Adv Catalyt Mat & Technol, Sch Petrochem Engn, Changzhou 213164, Jiangsu, Peoples R China
[2] Changzhou Vocat Inst Engn, Sch Chem & Pharmaceut Engn, Changzhou 213164, Jiangsu, Peoples R China
[3] Inst Chem Ind Forest Prod, Key Lab Biomass Energy & Mat, Key & Open Lab Forest Chem Engn, Natl Engn Lab Biomass Chem Utilizat, Nanjing, Peoples R China
来源：
SYNTHETIC COMMUNICATIONS | 2021年 / 51卷 / 01期
基金：
中国博士后科学基金;
关键词：
Annulation; C-H activation; isoquinolines; green solvent; ketoximes; C-H ACTIVATION/ANNULATION; BIOMASS-DERIVED SOLVENTS; CROSS-COUPLING REACTIONS; O BOND; SUBSTITUTED ISOQUINOLINES; INTERNAL ALKYNES; ACTIVATION; ARYL; ANNULATION; ACCESS;
D O I：
10.1080/00397911.2020.1819326
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A Rh (III)-catalyzed synthesis of isoquinoline derivatives fromN-hydroxyoximes and alkynesviaC-H activation/annulation process in biomass-derived gamma-valerolactone (GVL) has been developed. A series of functional groups were well tolerated, affording the desired products in good to excellent yields.
引用
收藏
页码：94 / 102
页数：9
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