Rh(III)-catalyzed synthesis of isoquinolines fromN-hydroxyoximes and alkynes inγ-valerolactone

被引：3

作者：

Jiang, Kuan-Chang ^{[1
]}

Wang, Liang ^{[1
,2
]}

Chen, Qun ^{[1
]}

He, Ming-Yang ^{[1
]}

Shen, Ming-Gui ^{[3
]}

Zhang, Zhi-Hui ^{[1
]}

机构：

[1] Changzhou Univ, Jiangsu Key Lab Adv Catalyt Mat & Technol, Sch Petrochem Engn, Changzhou 213164, Jiangsu, Peoples R China

[2] Changzhou Vocat Inst Engn, Sch Chem & Pharmaceut Engn, Changzhou 213164, Jiangsu, Peoples R China

[3] Inst Chem Ind Forest Prod, Key Lab Biomass Energy & Mat, Key & Open Lab Forest Chem Engn, Natl Engn Lab Biomass Chem Utilizat, Nanjing, Peoples R China

来源：

SYNTHETIC COMMUNICATIONS | 2021年 / 51卷 / 01期

基金：

中国博士后科学基金;

关键词：

Annulation; C-H activation; isoquinolines; green solvent; ketoximes; C-H ACTIVATION/ANNULATION; BIOMASS-DERIVED SOLVENTS; CROSS-COUPLING REACTIONS; O BOND; SUBSTITUTED ISOQUINOLINES; INTERNAL ALKYNES; ACTIVATION; ARYL; ANNULATION; ACCESS;

D O I：

10.1080/00397911.2020.1819326

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A Rh (III)-catalyzed synthesis of isoquinoline derivatives fromN-hydroxyoximes and alkynesviaC-H activation/annulation process in biomass-derived gamma-valerolactone (GVL) has been developed. A series of functional groups were well tolerated, affording the desired products in good to excellent yields.

引用

页码：94 / 102

页数：9

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