Rhodium Complexes Bearing 1,10-Phenanthroline Analogue Bis-NHC Ligands Are Active Catalysts for Transfer Hydrogenation of Ketones

被引：35

作者：

Gierz, Verena ^{[1
]}

Urbanaite, Aurelija ^{[1
]}

Seyboldt, Alexander ^{[1
]}

Kunz, Doris ^{[1
]}

机构：

[1] Univ Tubingen, Inst Anorgan Chem, D-72076 Tubingen, Germany

来源：

ORGANOMETALLICS | 2012年 / 31卷 / 21期

关键词：

N-HETEROCYCLIC CARBENE; EFFICIENT TRANSFER HYDROGENATION; OXIDATIVE ADDITION; IRIDIUM COMPLEXES; C-H; COORDINATION; REACTIVITY; DONOR; ACTIVATION; SILVER;

D O I：

10.1021/om3008103

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Synthesis of a new example of the pyridazine annelated bis(N-heterocyclic carbene) ligand 3b (vegi) bearing benzyl substituents. is reported, as well as the synthesis of its Cationic Rh(cod) complex 5b. The mechanism of formation of the [Rh(cod)(vegi)](+) complexes was investigated, showing stepwise deprotonation of the imidazolium moieties via the mono-carbene imidazolium Rh(cod)Cl species 4. The [Rh(cod)(vegi)](+) 4 complexes 5a,b show catalytic activity in the transfer hydrogenation of even sterically hindered ketones.

引用

页码：7532 / 7538

页数：7

共 50 条

[31] METAL COMPLEXES OF 1,10-PHENANTHROLINE DERIVATIVES .I. BIS COMPLEXES OF 2-CARBOXY-1,10-PHENANTHROLINE WITH 1ST ROW TRANSITION METAL IONS
GOODWIN, HA
SYLVA, RN
AUSTRALIAN JOURNAL OF CHEMISTRY, 1967, 20 (02) : 217 - &
[32] Intracomplex π-π stacking interaction between adjacent phenanthroline molecules in complexes with rare-earth nitrates: Crystal and molecular structures of bis(1,10-Phenanthroline)trinitratoytterbium and bis(1,10-Phenanthroline)trinitratolanthanum
Sadikov, G. G.
Antsyshkina, A. S.
Rodnikova, M. N.
Solonina, I. A.
CRYSTALLOGRAPHY REPORTS, 2009, 54 (01) : 48 - 58
[33] Intracomplex π-π stacking interaction between adjacent phenanthroline molecules in complexes with rare-earth nitrates: Crystal and molecular structures of bis(1,10-Phenanthroline)trinitratoytterbium and bis(1,10-Phenanthroline)trinitratolanthanum
G. G. Sadikov
A. S. Antsyshkina
M. N. Rodnikova
I. A. Solonina
Crystallography Reports, 2009, 54 : 48 - 58
[34] Dioxochromium(V) complexes with 1,10-phenanthroline and 2,2′-bipyridine ligands
Sulfab, Y
Nasreldin, M
TRANSITION METAL CHEMISTRY, 2001, 26 (1-2) : 147 - 149
[35] Alkene epoxidation catalyzed by manganese complexes with electronically modified 1,10-phenanthroline ligands
Goldsmith, Christian R.
Jiang, Wenchan
INORGANICA CHIMICA ACTA, 2012, 384 : 340 - 344
[36] Syntheses and properties of cyclometalated ruthenium(II) complexes with 1,10-phenanthroline and phenylphthalazine ligands
Ji, Jiao
Li, Guo-Qiang
Xu, Ya-Qin
Jia, Ai-Quan
Zhang, Qian-Feng
ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 2019, 74 (03): : 267 - 271
[37] Synthesis and Luminescence Study of Europium Complexes with Carboxylic Acid and 1,10-Phenanthroline Ligands
QIAN Dong-jin and ZHANG Shu-zhen (Department of Chemistry
Chemical Research in Chinese Universities, 1993, (03) : 181 - 187
[38] Coinage metal-ethylene complexes of sterically demanding 1,10-phenanthroline ligands
Karade, Deepika V.
Phan, Vo Quang Huy
Dias, H. V. Rasika
DALTON TRANSACTIONS, 2024, 53 (25) : 10426 - 10433
[39] Photophysical, electrochemical and electrochromic behavior of transition metal complexes with 1,10-phenanthroline ligands
Zhou, Qian-hua
Du, Kui
Qiang, Liang
Guo, Jia-hao
He, Qi
Wu, Ye
Tang, Qian
Shen, Wei
Gong, Cheng-bin
DYES AND PIGMENTS, 2023, 219
[40] Dioxochromium(V) complexes with 1,10-phenanthroline and 2,2′-bipyridine ligands
Yousif Sulfab
Mohamed Nasreldin
Transition Metal Chemistry, 2001, 26 : 147 - 149

← 1 2 3 4 5 →