Syntheses and properties of cyclometalated ruthenium(II) complexes with 1,10-phenanthroline and phenylphthalazine ligands

被引：5
|
作者：
Ji, Jiao [1 ]
Li, Guo-Qiang [1 ]
Xu, Ya-Qin [1 ]
Jia, Ai-Quan [1 ]
Zhang, Qian-Feng [1 ]
机构：
[1] Anhui Univ Technol, Inst Mol Engn & Appl Chem, Maanshan 243002, Anhui, Peoples R China
来源：
ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES | 2019年 / 74卷 / 03期
关键词：
1,10-phenanthroline; 1-phenoxy-4-phenyl-phthalazines; crystal structure; cyclometalated complex; phthalazine; ruthenium; CYCLORUTHENATED COMPLEXES;
D O I：
10.1515/znb-2018-0211
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Treatment of cis-[RuCl2(phen)(2)] center dot 2H(2)O (phen =1,10-phenanthroline) with 1-(2,6-diisopropyl phenoxy)-4-phenylphthalazine (HL1) or 1-(2,6-dimethylphenoxy)-4-phenylphthalazine (HL2) in the presence of AgPF6 afforded two cyclometalated ruthenium(II) complexes, [Ru(kappa(2)-C,N-L1)(phen)(2)](PF6) (1) and [Ru(kappa(2)-C,N-L2)(phen)(2)](PF6) (2), respectively. The two complexes have been characterized by UV-vis and luminescence spectroscopy. The structure of 1.1.5H(2)O has been determined by single-crystal X-ray diffraction.
引用
收藏
页码：267 / 271
页数：5
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