Syntheses and properties of cyclometalated ruthenium(II) complexes with 1,10-phenanthroline and phenylphthalazine ligands

被引：5

作者：

Ji, Jiao ^{[1
]}

Li, Guo-Qiang ^{[1
]}

Xu, Ya-Qin ^{[1
]}

Jia, Ai-Quan ^{[1
]}

Zhang, Qian-Feng ^{[1
]}

机构：

[1] Anhui Univ Technol, Inst Mol Engn & Appl Chem, Maanshan 243002, Anhui, Peoples R China

来源：

ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES | 2019年 / 74卷 / 03期

关键词：

1,10-phenanthroline; 1-phenoxy-4-phenyl-phthalazines; crystal structure; cyclometalated complex; phthalazine; ruthenium; CYCLORUTHENATED COMPLEXES;

D O I：

10.1515/znb-2018-0211

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Treatment of cis-[RuCl2(phen)(2)] center dot 2H(2)O (phen =1,10-phenanthroline) with 1-(2,6-diisopropyl phenoxy)-4-phenylphthalazine (HL1) or 1-(2,6-dimethylphenoxy)-4-phenylphthalazine (HL2) in the presence of AgPF6 afforded two cyclometalated ruthenium(II) complexes, [Ru(kappa(2)-C,N-L1)(phen)(2)](PF6) (1) and [Ru(kappa(2)-C,N-L2)(phen)(2)](PF6) (2), respectively. The two complexes have been characterized by UV-vis and luminescence spectroscopy. The structure of 1.1.5H(2)O has been determined by single-crystal X-ray diffraction.

引用

页码：267 / 271

页数：5

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