Rhodium Complexes Bearing 1,10-Phenanthroline Analogue Bis-NHC Ligands Are Active Catalysts for Transfer Hydrogenation of Ketones

被引：35

作者：

Gierz, Verena ^{[1
]}

Urbanaite, Aurelija ^{[1
]}

Seyboldt, Alexander ^{[1
]}

Kunz, Doris ^{[1
]}

机构：

[1] Univ Tubingen, Inst Anorgan Chem, D-72076 Tubingen, Germany

来源：

ORGANOMETALLICS | 2012年 / 31卷 / 21期

关键词：

N-HETEROCYCLIC CARBENE; EFFICIENT TRANSFER HYDROGENATION; OXIDATIVE ADDITION; IRIDIUM COMPLEXES; C-H; COORDINATION; REACTIVITY; DONOR; ACTIVATION; SILVER;

D O I：

10.1021/om3008103

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Synthesis of a new example of the pyridazine annelated bis(N-heterocyclic carbene) ligand 3b (vegi) bearing benzyl substituents. is reported, as well as the synthesis of its Cationic Rh(cod) complex 5b. The mechanism of formation of the [Rh(cod)(vegi)](+) complexes was investigated, showing stepwise deprotonation of the imidazolium moieties via the mono-carbene imidazolium Rh(cod)Cl species 4. The [Rh(cod)(vegi)](+) 4 complexes 5a,b show catalytic activity in the transfer hydrogenation of even sterically hindered ketones.

引用

页码：7532 / 7538

页数：7

共 50 条

[41] Emissive Ir(III) complexes bearing thienylamido groups on a 1,10-phenanthroline scaffold
Howarth, Ashlee J.
Majewski, Marek B.
Brown, Christopher M.
Lelj, Francesco
Wolf, Michael O.
Patrick, Brian O.
DALTON TRANSACTIONS, 2015, 44 (37) : 16272 - 16279
[42] COMPLEXES OF RHODIUM(3) AND IRIDIUM(3) WITH 2,2'-BIPYRIDYL AND 1,10-PHENANTHROLINE
GILLARD, RD
HEATON, BT
JOURNAL OF THE CHEMICAL SOCIETY A -INORGANIC PHYSICAL THEORETICAL, 1969, (03): : 451 - &
[43] Chelating bis-carbene rhodium(III) complexes in transfer hydrogenation of ketones and imines
Albrecht, M
Crabtree, RH
Mata, J
Peris, E
CHEMICAL COMMUNICATIONS, 2002, (01) : 32 - 33
[44] Rhodium(I)-NHC Complexes Bearing Bidentate Bis-Heteroatomic Acidato Ligands asgem-Selective Catalysts for Alkyne Dimerization
Galiana-Cameo, Maria
Borraz, Marina
Zelenkova, Yaroslava
Passarelli, Vincenzo
Lahoz, Fernando J.
Perez-Torrente, Jesus J.
Oro, Luis A.
Di Giuseppe, Andrea
Castarlenas, Ricardo
CHEMISTRY-A EUROPEAN JOURNAL, 2020, 26 (43) : 9598 - 9608
[45] Synthesis, structure, and catalytic ethylene oligomerization of nickel complexes bearing 2-pyrazolyl substituted 1,10-phenanthroline ligands
Yang, Yue
Yang, Peiju
Zhang, Cui
Li, Gang
Yang, Xiao-Juan
Wu, Biao
Janiak, Christoph
JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2008, 296 (1-2) : 9 - 17
[46] Mono- and bis-guanosine adducts of platinum complexes with carrier ligands having in-plane steric bulk: The case of 1,10-phenanthroline and 2,9-dimethyl-1,10-phenanthroline
Margiotta, N
Papadia, P
Fanizzi, FP
Natile, G
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2003, (06) : 1136 - 1144
[47] TRANSFER OF HYDROGEN FROM ALCOHOLS TO KETONES CATALYZED BY IRIDIUM COMPLEXES WITH 2,2'-BIPYRIDINE, 1,10-PHENANTHROLINE, AND THEIR DERIVATIVES
MESTRONI, G
ZASSINOVICH, G
CAMUS, A
MARTINELLI, F
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1980, 198 (01) : 87 - 96
[48] PHOSPHORESCENCE DECAY OF 2,2'-DIPYRIDYL, 1,10-PHENANTHROLINE AND THEIR TRIS AND BIS COMPLEXES WITH RHODIUM(III) AT LOW-TEMPERATURES
HALPER, W
DEARMOND, MK
CHEMICAL PHYSICS LETTERS, 1974, 24 (01) : 114 - 116
[49] Cobalt(II) complexes bearing 2-imino-1,10-phenanthroline ligands: synthesis, characterization and ethylene oligomerization
Jie, Suyun
Zhang, Shu
Wedeking, Katrin
Zhang, Wen
Ma, Hongwei
Lu, Xiaoming
Deng, Yuan
Sun, Wen-Hua
COMPTES RENDUS CHIMIE, 2006, 9 (11-12) : 1500 - 1509
[50] Platinum(II) Complexes with 1,10-Phenanthroline and Hydrophilic Alkoxyacetate Ligands as Potential Antitumor Agents
Sun, Yanyan
Wei, Huaixin
Zhang, Qiang
Zhao, Xin
CHEMISTRY & BIODIVERSITY, 2019, 16 (01)

← 1 2 3 4 5 →