Influence of temperature on production of water-in-oil emulsions by microchannel emulsification

In this paper, we report the influence of temperature on the production characteristics of water-in-oil (W/O) emulsions by microchannel emulsification (MCE). The temperature of an emulsification module including a hydrophobic microchannel (MC) array chip was controlled between 10 degrees C and 55 degrees C. The continuous phase was a decane oil solution containing 5 wt% tetraglycerin monolaurate condensed ricinoleic acid ester as a surfactant. The dispersed phase was a Milli-Q water solution containing 1 wt% of sodium chloride and 5 wt% of polyethylene glycol. The contact angle of the dispersed phase to the MC wall exceeded 152 degrees, strongly suggesting that the MC array surfaces are not wetted by the dispersed phase during MCE. At the breakthrough pressure of the dispersed phase, monodisperse W/O emulsions with coefficient of variation below 5% were produced via hydrophobic MC arrays, irrespective of the temperature. At each operating temperature, the resultant droplet diameter was also almost constant below a critical flow velocity of the dispersed phase. The maximum droplet generation rate from a channel gradually increased with increasing operating temperature due to the decrease in viscosity of both phases. An adapted capillary number that considers the influence of the wettability and surfactant adsorption had a low maximum/minimum value ratio of 1.2. (C) 2012 Elsevier B.V. All rights reserved.