Carbonylation with CO2 and Phosphorus Electrophiles: A Convenient Method for the Synthesis of 2-Oxazolidinones from 1,2-Amino Alcohols

被引：20
|
作者：
Paz, Jairo [1 ]
Perez-Balado, Carlos [1 ]
Iglesias, Beatriz [1 ]
Munoz, Luis [1 ]
机构：
[1] Univ Vigo, Dept Quim Organ, Vigo 36310, Spain
来源：
SYNLETT | 2009年 / 03期
关键词：
Oxazolidinones; 1,2-amino alcohols; carbonylation; guanidines; CATALYZED OXIDATIVE CARBONYLATION; BETA-AMINO ALCOHOLS; CARBON-DIOXIDE; ASYMMETRIC-SYNTHESIS; SELECTIVE SYNTHESIS; CHIRAL AUXILIARIES; GUANIDINE BASES; MILD CONDITIONS; PALLADIUM; OXAZOLIDIN-2-ONES;
D O I：
10.1055/s-0028-1087531
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
2-Oxazolidinones were prepared in good yields from 1,2-amino alcohols and CO2 in the presence of tetrarnethyl-phenylguanidine (PhTMG) as a base and a variety of phosphorus electrophiles under mild conditions. This procedure is advantageous over previous methodologies and relies on a novel carbonylation procedure that utilizes nontoxic CO2 and phosphorus electrophiles.
引用
收藏
页码：395 / 398
页数：4
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