Synthesis of Carbonates from Alcohols and CO2

被引：57
|
作者：
Kindermann, Nicole [1 ]
Jose, Tharun [1 ]
Kleij, Arjan W. [1 ,2 ]
机构：
[1] Barcelona Inst Sci & Technol, Inst Chem Res Catalonia ICIQ, Av Paisos Catalans 16, Tarragona 43007, Spain
[2] Pg Lluis Co 23, Catalan Inst Res & Adv Studies ICREA, Barcelona 08010, Spain
来源：
TOPICS IN CURRENT CHEMISTRY | 2017年 / 375卷 / 01期
关键词：
Carbon dioxide; Carboxylative cyclization; Cyclic carbonates; Diols; Heterogeneous catalysis; Homoallylic alcohols; Homogeneous catalysis; Linear carbonates; Propargylic alcohols; METHYLENE CYCLIC CARBONATES; DIMETHYL CARBONATE; GLYCEROL CARBONATE; ORGANIC CARBONATES; CEO2; CATALYST; PROPARGYLIC ALCOHOLS; PROPYLENE CARBONATE; SELECTIVE SYNTHESIS; DIALKYL-CARBONATES; MILD CONDITIONS;
D O I：
10.1007/s41061-016-0101-8
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Alcohols are ubiquitous compounds in nature that offer modular building blocks for synthetic chemistry. Here we discuss the most recent development of different classes of alcohols and their coupling chemistry with carbon dioxide as to afford linear and cyclic carbonates, the challenges associated with their formation, and the potential of this chemistry to revive a waste carbon feed stock.
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页数：28
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