Synthesis of carbonates directly from 1 atm CO2 and alcohols using CH2Cl2

被引：27
|
作者：
Yamazaki, Yusuke [1 ]
Kakuma, Kasumi [1 ]
Du, Ya [1 ]
Saito, Susumu [1 ,2 ]
机构：
[1] Nagoya Univ, Grad Sch Sci, Dept Chem, Chikusa Ku, Nagoya, Aichi 4648602, Japan
[2] Nagoya Univ, Inst Adv Res, Chikusa Ku, Nagoya, Aichi 4648601, Japan
来源：
TETRAHEDRON | 2010年 / 66卷 / 51期
关键词：
1 atm Carbon dioxide; Dichloromethane; Carbonate; Alcohol; Cesium carbonate; PRIMARY ALIPHATIC-AMINES; DIMETHYL CARBONATE; CATALYZED SYNTHESIS; CARBOXYLIC-ACIDS; PROPYLENE CARBONATE; NAY FAUJASITE; DIOXIDE; ALLYL; HYDROGENATION; PALLADIUM;
D O I：
10.1016/j.tet.2010.10.051
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
We introduced here a new one-pot, general procedure for the preparation of dialkyl carbonates from alcohols in a straightforward fashion under 1 atm pressure of CO2 using Cs2CO3 and CH2Cl2 as key reagents. (C) 2010 Elsevier Ltd. All rights reserved.
引用
收藏
页码：9675 / 9680
页数：6
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