Carbonylation with CO2 and Phosphorus Electrophiles: A Convenient Method for the Synthesis of 2-Oxazolidinones from 1,2-Amino Alcohols

被引：20

作者：

Paz, Jairo ^{[1
]}

Perez-Balado, Carlos ^{[1
]}

Iglesias, Beatriz ^{[1
]}

Munoz, Luis ^{[1
]}

机构：

[1] Univ Vigo, Dept Quim Organ, Vigo 36310, Spain

来源：

SYNLETT | 2009年 / 03期

关键词：

Oxazolidinones; 1,2-amino alcohols; carbonylation; guanidines; CATALYZED OXIDATIVE CARBONYLATION; BETA-AMINO ALCOHOLS; CARBON-DIOXIDE; ASYMMETRIC-SYNTHESIS; SELECTIVE SYNTHESIS; CHIRAL AUXILIARIES; GUANIDINE BASES; MILD CONDITIONS; PALLADIUM; OXAZOLIDIN-2-ONES;

D O I：

10.1055/s-0028-1087531

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

2-Oxazolidinones were prepared in good yields from 1,2-amino alcohols and CO2 in the presence of tetrarnethyl-phenylguanidine (PhTMG) as a base and a variety of phosphorus electrophiles under mild conditions. This procedure is advantageous over previous methodologies and relies on a novel carbonylation procedure that utilizes nontoxic CO2 and phosphorus electrophiles.

引用

页码：395 / 398

页数：4

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