Advanced porous electrodes with flow channels for vanadium redox flow battery

被引:81
|
作者
Bhattarai, Arjun [1 ,2 ]
Wai, Nyunt [2 ]
Schweiss, Ruediger [3 ]
Whitehead, Adam [4 ]
Lim, Tuti M. [5 ]
Hng, Huey Hoon [1 ]
机构
[1] Nanyang Technol Univ, Sch Mat Sci & Engn, Singapore, Singapore
[2] Nanyang Technol Univ, Energy Res Inst, Singapore, Singapore
[3] SGL Carbon GmbH, Meitingen, Germany
[4] Gildemeister Energy Storage GmbH, Wiener Neudorf, Austria
[5] Nanyang Technol Univ, Sch Civil & Environm Engn, Singapore, Singapore
关键词
Vanadium redox flow battery; Porous electrodes; Flow distribution; Flow channels; Flow-through; PERFORMANCE; FIELD;
D O I
10.1016/j.jpowsour.2016.11.113
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Improving the overall energy efficiency by reducing pumping power and improving flow distribution of electrolyte, is a major challenge for developers of flow batteries. The use of suitable channels can improve flow distribution through the electrodes and reduce flow resistance, hence reducing the energy consumption of the pumps. Although several studies of vanadium redox flow battery have proposed the use of bipolar plates with flow channels, similar to fuel cell designs, this paper presents the use of flow channels in the porous electrode as an alternative approach. Four types of electrodes with channels: rectangular open channel, interdigitated open cut channel, interdigitated circular poked channel and cross poked circular channels, are studied and compared with a conventional electrode without channels. Our study shows that interdigitated open channels can improve the overall energy efficiency up to 2.7% due to improvement in flow distribution and pump power reduction while interdigitated poked channel can improve up to 2.5% due to improvement in flow distribution. (C) 2016 Elsevier B.V. All rights reserved.
引用
收藏
页码:83 / 90
页数:8
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