Suzuki and Heck Processes for the Synthesis of New Anthraquinone-Based Glycoconjugated Dyes

被引：2

作者：

Calugi, Lorenzo ^{[1
]}

Bonanni, Marco ^{[2
]}

Corsi, Massimo ^{[1
]}

Chimichi, Stefano ^{[1
]}

Bianchini, Roberto ^{[1
]}

机构：

[1] Univ Florence, Dept Chem Ugo Schiff, Via Lastruccia 3-13, I-50019 Sesto Fiorentino, FI, Italy

[2] Glycolor Srl, Via Madonna Piano 6, I-50019 Sesto Fiorentino, FI, Italy

来源：

CHEMISTRYSELECT | 2018年 / 3卷 / 08期

关键词：

anthraquinone dyes; glycoconjugation; naturalization; Pd cross-coupling reactions; ARYL HALIDES; CATALYST; FLUORESCENCE; DERIVATIVES; REACTIVITY; REDUCTION;

D O I：

10.1002/slct.201702884

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Starting from a bromo-anthraquinone dye, different aryl- and styril- derivates are obtained following Suzuki and Heck procedures. Bathochromic shifts are displayed for the products, if compared to the starting anthraquinone dye. Two of these dyes, coming from either the Suzuki and the Heck processes, have been glycosylated with a piperazinyl-lactose derivative, so that two naturalized species are finally obtained. Therefore, the disperse chromophores were transformed in water soluble direct species. These kinds of dyes allow to avoid azo- structures, that are object of growing criticism in the European Union due to their environmental impact.

引用

页码：2235 / 2239

页数：5

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