Alkaline Earth Metal-Organic Frameworks Based on Tetratopic Anthraquinone-Based Linkers: Synthesis, Characterization, and Photochemical Applications

被引：2
|
作者：
de Carvalho, Joao Guilherme M. [1 ,2 ]
Geisser, Korbinian [1 ,2 ]
Weishaeupl, Sebastian J. [1 ,2 ]
Fischer, Roland A. [1 ,2 ]
Poethig, Alexander [1 ,2 ]
机构：
[1] Tech Univ Munich, Catalysis Res Ctr, Chair Inorgan & Met Organ Chem, D-85748 Garching, Germany
[2] Tech Univ Munich, Dept Chem, D-85748 Garching, Germany
来源：
INORGANIC CHEMISTRY | 2022年 / 61卷 / 40期
关键词：
ACTIVATION;
D O I：
10.1021/acs.inorgchem.2c01643
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A tetratopic bis(diphenylamino)anthraquinone link-er is presented, and its physicochemical properties are evaluated. The linker is shown to successfully coordinate alkaline earth metals leading to four new reported metal-organic frameworks (MOFs), which have been fully characterized, including single-crystal X-ray diffraction. The physicochemical and emissive properties of the MOF materials are investigated and compared to those of the uncoordinated ligand. Finally, the catalytic behavior of the ligand and the MOF materials toward the photooxidation of sulfides is described.
引用
收藏
页码：15831 / 15840
页数：10
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