Reactions of tin tetrachloride with diethyl glutarate. Crystal structures of [Sn2Cl8{mu-C3H6(CO(2)Et)(2)}(2)]center dot 2CH(2)Cl(2) and cis-[SnCl4(H2O)(2)]center dot C3H6(CO(2)Et)(2)

被引：3
|
作者：
Sobota, P
Szafert, S
Glowiak, T
机构：
来源：
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1996年 / 04期
关键词：
D O I：
10.1039/dt9960000439
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The dimeric compound [Sn2Cl8{mu-C3H6(CO(2)Et)(2)}(2)]. 2CH(2)Cl(2) 1 has been prepared by direct reaction of SnCl4 with diethyl glutarate in CH2Cl2 and its crystal structure has been determined. Each tin atom is octahedrally co-ordinated by four chlorine atoms and two mutually cis carbonyl oxygen atoms of two bridging diethyl glutarate molecules. During the crystallization of 1 the compound cis-[SnCl4(H2O)(2)]. C3H6(CO(2)Et)(2) 2 was formed under the influence of moisture. Its crystal structure revealed a monomeric complex of Sn-IV in which each tin atom is surrounded octahedrally by four chlorine atoms and two water oxygen atoms. A non-co-ordinated ester molecule is hydrogen bonded through carbonyl oxygen atoms to one water molecule.
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页码：439 / 442
页数：4
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